Anatoly Alexander - Berkeley Heights NJ Mikhail Raykh - East Brunswick NJ
Assignee:
ISP Investments Inc. - Wilmington DE
International Classification:
C07D207267
US Classification:
548543
Abstract:
A single stage process, with recirculation of reactants, is provided herein for making N-vinylpyrrolidone or N-vinyl caprolactam at a high reaction rate and selectivity and at a predetermined conversion per pass. In this process a reaction mixture is formed by saturating a non-aqueous, liquid mixture of recirculating lactam, vinyl lactam and catalyst with acetylene at low temperatures and pressures to provide a high concentration of acetylene in the liquid, pumping the saturated solution into a reactor, reacting the mixture as a single liquid phase, cooling the reaction product, withdrawing a portion of the cooled product, recirculating the rest into the reaction mixture, and continuously feeding additional lactam and catalyst therein.
Heterocyclic Quaternary Salts Of Para-Dialkylamino Benzamide Derivatives
Ratan K. Chaudhuri - Butler NJ Anatoly Alexander - Berkeley Heights NJ Anna A. Gripp - Whippany NJ
Assignee:
ISP Van Dyk Inc. - Belleville NJ
International Classification:
A61K 706 A61K 742 C07D26304
US Classification:
424 60
Abstract:
This invention relates to non-hydrolyzable, non-irritating, hair, skin and textile substantive quaternary ammonium salts of a para-dialkylamino benzamide having the formula ##STR1## wherein R' and R" are each selected from the group of C. sub. 1 to C. sub. 2 alkyl; n is an integer having a value of from 2 to 6; R is an alkyl radical having from 1 to 30 carbon atoms; R. sub. 1 and R. sub. 2 together with the attached cationic nitrogen atom forms a 5 to 6-membered heterocyclic ring containing a hetero oxygen atom in addition to the heteronitrogen atom and is selected from the group of ##STR2## and X is an anion. These benzamide heterocyclic derivatives are active sunscreening agents which are usefully employed at a concentration of from about 0. 5 to about 10 wt. % in a formulation requiring protection against the harmful effects of sunlight, such as skin burn, hair damage, color fading, etc.
Process For Preparation Of Cinnamate Sunscreen Agents
Anatoly Alexander - Berkeley Heights NJ Ratan K. Chaudhuri - Butler NJ
Assignee:
ISP Van Dyk Inc. - Belleville NJ
International Classification:
C07C 6976
US Classification:
560 55
Abstract:
This invention relates to an improved process for the manufacture of cinnamate compounds, particularly sunscreen agents, useful in cosmetic skin and hair care formulations. The process comprises: (a) dissolving a water insoluble C. sub. 1 to C. sub. 4 alkoxy benzaldehyde and a C. sub. 1 to C. sub. 4 alkyl acetate in a common hydrocarbon solvent; (b) reacting the resulting solution in the presence of a strong alkali metal-containing base under mild conditions to form a mixture containing the corresponding C. sub. 1 to C. sub. 4 alkyl C. sub. 1 to C. sub. 4 alkoxy cinnamate, the alkali metal salt of the enol corresponding to the C. sub. 1 to C. sub. 4 alkyl C. sub. 1 to C. sub. 4 alkoxy cinnamate, the alkali metal salt of a C. sub. 1 to C. sub. 4 alkoxycinnamic acid, and a C. sub. 1 to C. sub. 4 alkanol; (c) acidifying the resulting mixture with from about 0.
Ratan K. Chaudhuri - Butler NJ Anatoly Alexander - Berkeley Heights NJ Anna A. Gripp - Whippany NJ
Assignee:
ISP Van Dyk Inc. - Belleville NJ
International Classification:
A61K 706 A61K 742 C07C22900
US Classification:
424 60
Abstract:
This invention relates to non-hydrolyzable, non-irritating, hair, skin and textile substantive quaternary salts of p-dialkylaminobenzamides having the formula ##STR1## wherein R' and R" are each selected from the group of C. sub. 1 to C. sub. 2 alkyl; n is an integer having a value of from 2 to 3; R is an alkyl radical having from 10 to 18 carbon atoms; R. sub. 1 and R. sub. 2 are each selected from the group of C. sub. 1 to C. sub. 2 alkyl, and X is an anion. These benzamide derivatives are active sunscreening agents which are usefully employed at a concentration of from about 0. 5 to about 10 wt. % in a formulation requiring protection against the harmful effects of sunlight, such as skin burn, hair damage, color fading, etc.
Quaternary Salts Of Para-Dialkylamino Benzamide Derivatives
Ratan K. Chaudhuri - Butler NJ Anatoly Alexander - Berkeley Heights NJ Anna A. Gripp - Whippany NJ
Assignee:
ISP Van Dyk Inc. - Belleville NJ
International Classification:
C07D24900 C07C23377 A61K 706 A61K 742
US Classification:
424 60
Abstract:
This invention relates to non-hydrolyzable, non-irritating, hair, skin and textile substantive quaternary ammonium salts of a para-dialkylamino benzamide having the formula ##STR1## wherein R' and R" are each selected from the group of C. sub. 1 to C. sub. 2 alkyl; n is an integer having a value of from 2 to 6; R is an alkyl radical having from 1 to 30 carbon atoms; R. sub. 1 and R. sub. 2 are each selected from the group of C. sub. 1 to C. sub. 4 alkyl, hydrogen and, alternatively, R. sub. 1 and R. sub. 2, together with the attached cationic nitrogen atom can form a 5 to 6-membered heterocyclic ring selected from the group of ##STR2## and X is an anion. These benzamide derivatives are active sunscreening agents which are usefully employed at a concentration of from about 0. 5 to about 10 wt. % in a formulation requiring protection against the harmful effects of sunlight, such as skin burn, hair damage, color fading, etc.
Process For Upgrading Gasolines And Other Hydrocarbon Mixtures
Anatoly Alexander - Berkeley Heights NJ Chuen Y. Yeh - Edison NJ George D. Suciu - Ridgewood NJ
Assignee:
ABB Lummus Crest Inc. - Bloomfield NJ
International Classification:
C10G 3504
US Classification:
208134
Abstract:
A process for upgrading gasolines and other hydrocarbon mixtures. The hydrocarbon mixture is contacted with a large pore zeolite catalyst in order to crack n-paraffins to form olefins and lower molecular weight n-paraffins, to cause the olefins to react with benzene in order to form alkylbenzenes, and to catalyze the isomerization of the n-paraffins to form i-paraffins. Preferably, all of the above reactions occur in a single reactant mixture in the presence of a zeolite catalyst having ten and/or twelve membered ring-type structures. The process of the invention reduces the benzene quantity of the hydrocarbon mixture and increases its octane number.
Process For The Isomerisation Of An Exo Double Bond
- Geneva 8, CH Koenraad VANHESSCHE - Feigeres, FR Anatoly ALEXANDER - Newark NJ, US
Assignee:
FIRMENICH SA - Geneva 8
International Classification:
C07C 45/67
Abstract:
The present invention concerns a process for the isomerisation of an exo double bond toward an endo double bond being performed in the presence of a catalyst system comprising palladium (Pd) or platinum (Pt) and molecular hydrogen or a hydrogen source.
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