Abstract:
A durable low T Sb-stabilized Mo+W phosphate based glass composition exhibiting superior resistance to attack by boiling water, humidity and acids resulting from the addition of Sb to Mo+W phosphate based glass compositions. Specifically, the present invention discloses a glass composition comprising in mol % on the oxide basis, of 0-40% R O where R includes the alkali metals (Li, Na, K, Rb or Cs) as well as Ag and Tl, 0-20% XO where X includes the alkaline earth metals (Mg, Ca, Sr or Ba) as well as Cu, Zn, Cd and Pb, 15-80% MoO +WO , 0. 5-60% Sb O , and 10-40% P O. Additionally, the Sb-stabilized Mo+W phosphate based glass composition can contain a total of 0-5%, in mole percent (mol %) on the oxide basis, of glass forming oxides including, but not limited to, B O , Al O , SiO , TeO , Ga O3, GeO , transition metal and rare earth metal oxides, or mixtures thereof. The resulting durable Sb-stabilized Mo+W phosphate based glass compositions are particularly useful as refractory adhesives, sealing glass frits, and overcladding material for glass fiber.