Vinod M. Jalan - Manchester CT Calvin L. Bushnell - Glastonbury CT
Assignee:
United Technologies Corporation - Hartford CT
International Classification:
B01J 2118 B01J 2342
US Classification:
252447
Abstract:
Method for the production of highly dispersed electrochemically active platinum particles having an average diameter below about 50 A for use in electrodes for fuel cells. Platinum particles are formed by mixing chloroplatinic acid and sodium dithionite in water to provide a platinum containing colloidal dispersion which may be absorbed on a support material. Hydrogen peroxide can be mixed with the chloroplatinic acid and sodium dithionite to improve the stability of the platinum containing colloidal dispersion.
Alexander B. Shelekhin - Acton MA Calvin L. Bushnell - Glastonbury CT Michael S. Pien - Acton MA
Assignee:
ElectroChem, Inc. - Woburn MA
International Classification:
H01M 804
US Classification:
429 26
Abstract:
An air-cooled, hydrogen-air solid polymer electrolyte (SPE) fuel cell with a membrane electrode assembly operatively associated with a fluid flow plate having at least one plate cooling channel extending through the plate and at least one air distribution hole extending from a surface of the cathode flow field into the plate cooling channel.
Calvin L. Bushnell - Glastonbury CT Harold Russell Kunz - Vernon CT
Assignee:
United Technologies Corporation - Hartford CT
International Classification:
H01M 802
US Classification:
429 41
Abstract:
An electrolyte reservoir layer disposed behind and adjacent one of the catalyst layers of a fuel cell is porous and hydrophilic to the electrolyte. In one embodiment the reservoir layer includes impregnations of hydrophobic material on the catalyst facing surface thereof and holes leading from the other surface to the impregnations for providing reactant gas passages through the reservoir layer to the catalyst layer. The impregnations of hydrophobic material are designed to provide good distribution of the reactant gas into the catalyst layer without consuming a large volume of the reservoir. In a preferred embodiment the reservoir is also the electrode substrate whereby the catalyst layer is bonded to the surface thereof.
Vinod M. Jalan - Manchester CT Calvin L. Bushnell - Glastonbury CT
Assignee:
United Technologies Corporation - Hartford CT
International Classification:
B01J 2118 B01J 2342
US Classification:
429 44
Abstract:
The rate of platinum recrystallization of a platinum supported on carbon catalyst is reduced and the activity of the catalyst is increased by depositing porous carbon on and around the supported platinum crystallites and then heating the catalyst in an inert atmosphere or vacuum at a high temperature.
International Fuel Cells Corporation - South Windsor CT
International Classification:
H01M 814 H01M 802
US Classification:
429 13
Abstract:
Gaps occurring between a cathode substrate and a gas housing in a fuel cell interfere with electron transfer in the cell causing high cell internal resistance. To reduce the high resistance gaps are closed by coating the substrate with metal powder that expands during oxidation closing the gaps.
Vinod M. Jalan - Manchester CT Calvin L. Bushnell - Glastonbury CT
Assignee:
United Technologies Corporation - Hartford CT
International Classification:
B01J 2118 B01J 2342
US Classification:
429 44
Abstract:
The rate of platinum recrystallization of a platinum supported on carbon catalyst is reduced by depositing porous carbon on and around the supported platinum crystallites. The reduced rate of platinum recrystallization results in higher platinum surface areas over a period of time and therefore improves the performance of the catalyst. The porous carbon can be deposited by any suitable technique, a preferred method being to heat the supported platinum in the presence of carbon monoxide to decompose the carbon monoxide thereby depositing carbon on and around the platinum crystallites.
Electrolyte Matrix For Molten Carbonate Fuel Cells
Calvin L. Bushnell - Glastonbury CT Lawrence J. Bregoli - Southwick MA Craig R. Schroll - West Hartford CT
Assignee:
United Technologies Corporation - Hartford CT
International Classification:
H01M 486
US Classification:
429 41
Abstract:
Thru-cracks in the electrolyte retaining matrix of a molten carbonate fuel cell caused by thermal cycling of the cell between operating and room temperature are prevented by an improved matrix comprising a major proportion of submicron support particles and a minor proportion, perhaps only a few percent, of much larger crack attenuator particles. In one embodiment wherein the electrolyte is to be a binary lithium-potassium carbonates composition, the matrix comprises 90 volume percent submicron lithium aluminate support particles and 10 volume percent alumina crack attenuator particles with an average size of 100 microns.
Porous Carbon Body With Increased Wettability By Water
John A. S. Bett - Hamden CT Douglas J. Wheeler - Tolland CT Calvin Bushnell - Glastonbury CT
Assignee:
International Fuel Cells, Inc. - S. Windsor CT
International Classification:
B32B 326 H01M 216
US Classification:
4283077
Abstract:
Solid polymer membrane fuel cell product water which forms on the oxidant side of the membrane is removed from the active area of the cells in a fuel cell power plant by being absorbed into and wicked away from the active area by a porous carbon body which contacts the membrane. The carbon body may be an oxidant reactant flow field plate. The pores in the carbon body are partially filled with metal oxide granules which impart increased wettability and water absorption capacity to the carbon body.
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