Cary S. Marshall - Danville CA Scott D. Troyer - Pittsburg CA
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C25B 300
US Classification:
204 73R
Abstract:
The rate of production of 3,6-dichloropicolinic acid by reduction of tetrachloropicolinic acid in basic aqueous solution in a given cell can be considerably increased if a trichloropicolinic acid is added to the tetrachloropicolinic acid feed in substantially greater proportions than can result from in-situ reduction of the tetrachloro acid. Preferably, the trichloro acid is obtained by acid hydrolysis of by-products of symmetrical tetrachloropyridine manufacture by chlorination/chlorinolysis of 6-chloro-2-(trichloromethyl)pyridine.