Abstract:
A formaldehyde-free curable composition useful for binding nonwovens comprises (a) a polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts of the polyacid thereof; (b) an active hydrogen compound containing at least two active hydrogen groups selected from the group consisting of hydroxyl, primary amino, secondary amino, and mixtures thereof; and (c) one or more compounds selected from the group consisting of cyanamide, dicyandiamide, 1,2-mono- or di-(C. sub. 1 -C. sub. 6 alkyl) substituted-3-cyanoguanidines such as ethyl-3-cyanoguanidine, 1,2-diethyl-3-cyanoguanidine, and 1,2-diisopropyl-3-cyanoguanidine, and 1,2-mono- or di-(C. sub. 6 -C. sub. 12 aryl) substituted-3-cyanoguanidines, such as phenyl-dicyandiamide; and, optionally (d) an accelerator; wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said active hydrogen groups is from 1/0. 01 to about 1/3, and wherein said carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than 35% by weight with a fixed base.