Christine Elissa Stanley

US Patent:

60137525, Jan 11, 2000

Filed:

Jun 4, 1997

Appl. No.:

8/868793

Inventors:

Norman R. Mowrer - La Habra CA
Rhonda L. Linz - Benton AR
Roland L. Gasmena - Little Rock AR
Rudy Espinoza - Brea CA
Christine L. Stanley - Anaheim CA
Pritam S. Dhaliwal - Upland CA

Assignee:

Ameron International Corporation - Pasadena CA

International Classification:

C08G 7706

US Classification:

528 26

Abstract:

Halogenated resin compositions are prepared without using halogen acids by combining at least one silicone intermediate, with an optional silane, an organic halogen-containing ingredient having functional groups selected from the group consisting of hydroxy, amine, and carboxyl groups, and a resin selected from the group consisting of hydroxy- and epoxy-functional resins. One or more amine curing agent and/or catalyst selected from the group consisting of organometallic compounds, acids, bases, and mixtures thereof can optionally be added to facilitate ambient temperature curing of the resulting composition. The combined ingredients undergo hydrolysis reactions to form a halogenated organooxysilane that condenses to form a cross-linked halogenated polysiloxane composition. The resin also reacts with the condensing halogenated organooxysilane to introduce itself into the cross-linked halogenated polysiloxane and, thereby form the halogenated polysiloxane resin composition. The composition is prepare without using an inorganic halogen acid, and is fully-cured at ambient temperature by exposure to atmospheric moisture to form a protective film, or alternatively a composite, having improved properties of chemical, abrasion, corrosion, weather, flame, and ultraviolet resistance.