Vidyanatha A. Prasad - Leawood KS, US Robert D. Ingalls - Portage MI, US Stephen C. Slahck - Independence MO, US Christopher M. Tusa - Raymore MO, US
Assignee:
Bayer Cropscience LP - Research Triangle Park NC
International Classification:
C07F 9/165
US Classification:
558 87
Abstract:
The invention relates to a method of preparing O,O-dialkyl S-[2-(alkylthio)alkyl] phosphorodithioates by treating O,O-dialkyl dithiophosphoric acids with a base in the substantial absence of organic solvent to obtain O,O-dialkyl dithiophosphoric acid salts that are in turn treated with thioalcohol derivatives to form the O,O-dialkyl S-[2-(alkylthio)alkyl] phosphorodithioates.
Methods For Purifying O,O-Dialkyl S-[2-(Alkylthio)Alkyl] Phosphorodithioates
Vidyanatha Prasad - Leawood KS, US Robert Ingalls - Portage MI, US Stephen Slahck - Independence MO, US Christopher Tusa - Raymore MO, US Paul Nagy - Meerbusch, DE Michael Newcomer - Kansas City MO, US Donald Smith - Liberty MO, US
International Classification:
C07F009/02
US Classification:
558/146000
Abstract:
The invention relates to a method of purifying an O,O-dialkyl S-[2-(alkylthio)alkyl] phosphorodithioate by purging a sample containing a volatile and the O,O-dialkyl S-[2-(alkylthio)alkyl] phosphorodithioate with a gas.
Method For Reducing Deflagration Of Azinphos-Methyl
Horace G. Barnett - Kansas City MO Christopher M. Tusa - Grandview MO
Assignee:
Miles Inc. - Pittsburgh PA
International Classification:
A01N 2518
US Classification:
424405
Abstract:
A carbonate of an alkali metal is added to an azinphos-methyl powder formulation in an amount such that the carbonate is at least 10% by weight of the total mixture. Sodium bicarbonate is the preferred carbonate. The resultant mixtures are characterized by a reduced tendency toward deflagration at temperatures below 200. degree. C.
Process For Producing Dimethyl (2,2,2-Trichloro-1-Hydroxyethyl)-Phosphonate And Granular Formulations Thereof
Vidyanatha A. Prasad - Leawood KS Klaus Jelich - Overland Park KS Christopher M. Tusa - Kansas City MO Daniel E. Terry - Liberty MO Stephen C. Slahck - Blue Springs MO Scott P. Hensley - Kansas City MO
Assignee:
Bayer Corporation - Pittsburgh PA
International Classification:
B05D 700 A61K 3166 C07F 940
US Classification:
427220
Abstract:
The present invention relates to an integrated process for synthesizing dimethyl (2,2,2-trichloro-1-hydroxyethyl)-phosphonate and a process for impregnating the dimethyl (2,2,2-trichloro-1-hydroxyethyl)-phosphonate on to inert carrier granules. The process involves adding dimethyl phosphite to a reaction mixture containing chloral under anhydrous, inert conditions. The molar ratio of chloral to dimethyl phosphite used in the reaction mixture is from about 1. 0:1. 0 to about 1. 1:1. The impregnation process involves transferring molten dimethyl (2,2,2-trichloro-1-hydroxyethyl)-phosphonate into a process vessel and discharging weighed aliquots into a formulation vessel to form a granular product containing dimethyl (2,2,2-trichloro-1-hydroxyethyl)-phosphonate.
Chris Tusa (1999-2003), Juan Gamboa (1974-1978), Roger Dejean (1984-1988), Stephen Millet (1982-1986), Jason Carney (1988-1992), Richard Hummel (1982-1986)