Embodiments of the present invention provide catalysts for production of hydrogen from methanol. In an embodiment, a Cu/Zn catalyst may be promoted by Zr and/or Ce, in addition to, in embodiments, Pd or another noble metal. In an embodiment, a chemical composition may have a Cu/Zn base catalyst with a promoter element of Ce, Zr, and/or Pd or another noble metal. Methods of producing hydrogen using such catalysts are also provided.
Device For Treating Gases Using Microfabricated Matrix Of Catalyst
A method of microfabricating a matrix of evenly distributed catalytic articles, with the matrix then being used to treat reactants in a stream of gases. The matrix is created by depositing areas of conductive material on a nonconductive base wafer or substrate, and then depositing catalyst particles in electrical communication with the conductive material so that a series of localized electrical fields can be created upon the introduction of a power source. A dielectric material surrounding the catalyst particles can be altered by increasing the applied voltage, thereby increasing the strength of the electrical field. A device so constructed is placed in a stream of gases, and the localized electrical fields alter the selectivity and the reactivity of the reactants in the stream of gases.
Nickel Catalyzed Carbon Infiltration Of Carbon Fiber Substrates
Eduardo E. Wolf - Granger IN Paul McAllister - Houston TX
Assignee:
Unitersity of Notre Dame du Lac - Notre Dame IN
International Classification:
D04H 158
US Classification:
428289
Abstract:
A catalytic carbon formation technique in a carbon fiber substrate is disclosed. The carbon fiber substrate is first impregnated with a catalyst and is thereafter heated in an atmosphere rich in carbon and hydrogen. The catalyst is typically a Group VIII metal and may be selected from the group consisting of iron, nickel and cobalt. An incipient wetness technique for impregnating the substrate is also disclosed. A salt of the catalyst is provided in solution and void volume of the substrate is determined. The carbon fiber is then impregnated with a volume of the solution which is incrementally less that the determined void volume.
Novel Method Of Catalyst Preparation By Pressure Dilution
Described is a method for the preparation of a reforming catalyst. The method comprises: (a) depositing a metal precursor on a porous support by wet impregnation, wherein the porous support is selected from the group consisting of a fumed silica, a fumed metal oxide, and combinations thereof; (b) drying the porous support after depositing the metal precursor to form a powder; (c) adding additional porous support to the powder to form a diluted powder; and (d) pressing the diluted powder to form pellets.
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