George Allen Young

US Patent:

53827260, Jan 17, 1995

Filed:

Nov 22, 1993

Appl. No.:

8/156142

Inventors:

George H. Young - League City TX
Joseph A. Cowfer - Medina OH
Victor J. Johnston - Silver Lake OH

Assignee:

The Geon Company - Independence OH

International Classification:

C07C 17156

US Classification:

570243

Abstract:

The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.

US Patent:

52927032, Mar 8, 1994

Filed:

Jul 28, 1992

Appl. No.:

7/920721

Inventors:

George H. Young - League City TX
Joseph A. Cowfer - Medina OH
Victor J. Johnston - Silver Lake OH

Assignee:

The Geon Company - Independence OH

International Classification:

B01J 2372
B01J 2378
B01J 2310

US Classification:

502303

Abstract:

The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.