A process which produces a krypton-xenon concentrate from a liquid feed while also producing a liquid product substantially free of rare gases. The process employs an integral heat pump circuit to carry out the separation in an energy-efficient manner.
Deuterium is concentrated in a hydrogen-water isotopic exchange process enhanced by the use of catalyst materials in cold and hot tower contacting zones. Water is employed in a closed liquid recirculation loop that includes the cold tower, in which deuterium is concentrated in the water, and the upper portion of the hot tower in which said deuterium is concentrated in the hydrogen stream. Feed water is fed to the lower portion of said hot tower for contact with the circulating hydrogen stream. The feed water does not contact the water in the closed loop. Catalyst employed in the cold tower and the upper portion of the hot tower, preferably higher quality material, is isolated from impurities in the feed water that contacts only the catalyst, preferably of lower quality, in the lower portion of the hot zone. The closed loop water passes from the cold zone to the dehumidification zone, and a portion of said water leaving the upper portion of the hot tower can be passed to the humidification zone and thereafter recycled to said closed loop. Deuterium concentration is enhanced in said catalytic hydrogen-water system while undue retarding of catalyst activity is avoided.
A porous composite structure comprising a sintered mixture of metal particles and alumina particles, and a method for producing this composite. The composite is useful as a catalyst support, particularly in apparatus designed to reduce pollutant emissions from automobile engines.
Dry, High Purity Nitrogen Production Process And System
Ravi Prasad - East Amherst NY Oscar W. Haas - Cheektowaga NY Harry Cheung - Buffalo NY
Assignee:
Union Carbide Corporation - Danbury CT
International Classification:
F25J 302
US Classification:
62 24
Abstract:
Feed air to a prepurifier adsorption system/cryogenic air separation system for dry, high purity nitrogen and/or oxygen production is dried in a membrane dryer preferably characterized by a countercurrent flow path. Drying is enhanced by the use of purge gas on the permeate side of the membrane dryer, which adsorption system or cryogenic air separation system product or waste gas, dried feed air or ambient air being used as purge gas.
Cryogenic Rectification System For Enhanced Argon Production
Union Carbide Industrial Gases Technology Corporation - Danbury CT
International Classification:
F25J 304 F25J 306
US Classification:
62 22
Abstract:
A cryogenic rectification system comprising two cryogenic rectification plants wherein a fluid mixture comprising argon and nitrogen is withdrawn in a defined manner from the first plant and passed into the second plant such that argon production is enhanced to more than offset the additional separation power requirements.
Dante Patrick Bonaquist - Grand Island NY Harry Cheung - Williamsville NY Arun Acharya - East Amherst NY
Assignee:
Praxair Technology, Inc. - Danbury CT
International Classification:
F25D 900 F25J 300 F25B 900
US Classification:
62402
Abstract:
A method for generating refrigeration for application to a heat load, especially at very cold temperatures, using an environmentally benign working gas such as air and using an upstream precooling circuit to reduce or eliminate inefficiencies stemming from warm end pinch.
Cryogenic Air Separation Method For The Production Of Oxygen And Medium Pressure Nitrogen
Union Carbide Industrial Gases Technology Corporation - Danbury CT
International Classification:
F25J 300 F25J 302
US Classification:
62 38
Abstract:
A cryogenic air separation method for the production of oxygen and medium pressure nitrogen comprising a primary higher pressure column and an auxiliary smaller lower pressure stripping column wherein primary column bottom liquid is employed as stripping column downflow liquid and primary column top vapor condenses against stripping column bottom liquid to generate stripping vapor.
Process For The Production Of High Pressure Oxygen Gas
Oxygen gas is produced at greater than atmospheric pressure by separating air into oxygen-rich and nitrogen-rich fractions in a distillation column, removing the oxygen as liquid and pumping it to the desired pressure and subsequently vaporizing the pumped liquid oxygen by means of energy absorbed from a recirculation argon containing fluid.