Simon Ming-Kung Li - Houston TX Harry Frank - Houston TX Rupert R. Dominguez - Richmond TX
Assignee:
Resolution Performance Products LLC
International Classification:
C08G 5968
US Classification:
528 89, 422134, 422135, 523427, 525524, 528103
Abstract:
The present invention discloses a continuous process and the associated system for upstaging liquid epoxy resins to produce resins with higher molecular weight. The process comprises passing continuously (i) a liquid epoxy resin having a first molecular weight, (ii) a catalyst and (iii) a compound having at least one active hydrogen or reactive functional group capable of reacting with the liquid epoxy resin in the presence of the catalyst, flow through one or more reaction chambers and under conditions effective to produce a stream comprising an upstaged epoxy resin product having a second molecular weight. The second molecular weight is higher than the first molecular weight.
Copolymerization Of Polyethercyclicpolyols With Epoxy Resins
George C. Blytas - Houston TX Harry Frank - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07D31912
US Classification:
549378
Abstract:
Polyethercyclicpolyols are prepared by thermally condensing a polyol having at least three hydroxyl groups of which at least two of the hydroxyl groups are vicinal, precursors of the polyol, cyclic derivatives of the polyol, or mixtures thereof, and controlling process conditions to avoid substantial undesirable degeneration. Lower molecular weight polyethercyclicpolyols are copolymerized with epoxy resins to form higher molecular weight polyethercyclicpolyols.
Harold E. De Le Mare - Houston TX Harry Frank - Cherry Hill NJ
Assignee:
Shell Oil Company - Houston TX
International Classification:
C08G 3004
US Classification:
260 47EP
Abstract:
Improved stabilized acrylate resins compositions comprise the acrylate resin and a precise amount of a stabilizing acid having a pK. sub. a less than 2. 5 and having an anion having a nucleophilicity of less than 2. 5. An improved method of preparing stabilized acrylate resins comprises reacting the acrylate acid, epoxide, nucleophilic catalyst and stabilizing acid simultaneously to give the stabilized acrylate resin.
Polycondensation Of Epoxy Alcohols With Polyhdric Alcohols And Thermal Condensation To Form Polyethercyclicpolyols
Harry Frank - Houston TX George C. Blytas - Houston TX Anne H. Zuzich - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C08G 6504 C08G 6502
US Classification:
528421
Abstract:
Polyethercyclicpolyols are prepared by thermally condensing a polyol having at least three hydroxyl groups of which at least two of the hydroxyl groups are vicinal, precursors of the polyol, cyclic derivatives of the polyol, or mixtures thereof, and controlling process conditions to avoid substantial undesirable degeneration. Lower molecular weight polyethercyclicpolyols are polycondensed with epoxy alcohols to form higher molecular weight polyethercyclicpolyols.
Copolymerization Of Polyethercyclicpolyols With Epoxy Resins
George C. Blytas - Houston TX Harry Frank - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07D31912
US Classification:
549378
Abstract:
Polyethercyclicpolyols are prepared by thermally condensing a polyol having at least three hydroxyl groups of which at least two of the hydroxyl groups are vicinal, precursors of the polyol, cyclic derivatives of the polyol, or mixtures thereof, and controlling process conditions to avoid substantial undesirable degeneration. Lower molecular weight polyethercyclicpolyols are copolymerized with epoxy resins to form higher molecular weight polyethercyclicpolyols.
Polycondensation Of Epoxy Alcohols With Polyhydric Alcohols And Thermal Condensation To Form Polyethercyclicpolyols
Harry Frank - Houston TX George C. Blytas - Houston TX Anne H. Zuzich - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C08G 6504 C08G 6502
US Classification:
528403
Abstract:
Polyethercyclicpolyols are prepared by thermally condensing a polyol having at least three hydroxyl groups of which at least two of the hydroxyl groups are vicinal, precursors of the glycol, cyclic derivatives of the polyol, or mixtures thereof, and controlling process conditions to avoid substantial undesirable degeneration. Lower molecular weight polyethercyclicpolyols are polycondensed with epoxy alcohols to form higher molecular weight polyethercyclicpolyols.
Polyethercyclicpolyols From Epihalohydrins, Polyhydric Alcohols, And Metal Hydroxides
Anne H. Zuzich - Houston TX George C. Blytas - Houston TX Harry Frank - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07D31912
US Classification:
549378
Abstract:
Method for preparing polyethercyclicpolyol by heating a reaction mixture of an alkali or alkaline earth metal hydroxide with a polyol, adding epihalohydrin to initiate an addition reaction, and heating the mixture until the reaction is complete.
A method is disclosed for deactivating a hydrocarbyl phosphonium salt catalyst of an epoxy resin fusion reaction. The method involves contacting the hydrocarbyl phosphonium salt catalyst with a sulfonic acid, such as p-toluenesulfonic acid or methane sulfonic acid. The method is particularly suited for deactivation of moisture-resistant phosphonium salts such as methylene bis(triphenyl phosphonium halide)s.