Cyanohydrin esters are prepared by forming a mixture of an acyl cyanide, a carboxylic acid anhydride and an alkali metal borohydride and reacting the mixture at a temperature and for a time sufficient to form the cyanohydrin ester product of the acyl cyanide and carboxylic acid anhydride.
Process For Preparing Thienylglyoxylic Acids And Amides
Thienylglyoxylic acids and/or amides thereof are prepared by reacting thiophene carboxylic acid chloride with sodium cyanide and hydrolyzing the resulting product in a strong mineral acid.
Method For Preparing Glyoxylic Acids And Derivatives Thereof
James M. Photis - Ridgefield CT Fred S. Eiseman - Basking Ridge NJ Sidney M. Gister - Highland Park NJ
Assignee:
Stauffer Chemical Company - Westport CT
International Classification:
C07C 6966 C07C 59153
US Classification:
560 51
Abstract:
Glyoxylic acids or derivatives thereof are prepared by reacting an acyl nitrile compound with concentrated sulfuric acid in the presence of halide anion to form a first reaction product and then further reacting the first reaction product with a compound of the general formula ROH to form the desired glyoxylic acid or glyoxylic acid derivative.
Butyl-p-benzoylbenzoates are prepared by reacting a 4-(trichloromethyl) benzophenone with a butanol in the presence of an acid catalyst. These butyl-p-benzoylbenzoates are valuable photoinitiators for the polymerization of ethylenically unsaturated monomers.
Cyanohydrin esters are prepared by reacting an acyl halide represented by the structure ##STR1## with an acyl halide represented by the structure ##STR2## an alkali metal cyanide and an alkali metal borohydride.
Arylphosphinic acids are prepared by reacting an aryl compound with phosphorus trichloride in the presence of aluminum trichloride to form a first reaction product, adding the first reaction product to water to precipitate a second reaction product and then treating the second reaction product sequentially with a halogenating agent and with water to form the arylphosphinic acid.
Cyanohydrin esters are prepared by reacting an acyl cyanide represented by the structure ##STR1## with an acyl cyanide represented by the structure ##STR2## and an alkali metal borohydride.
Cyanohydrin esters are prepared by reacting a carboxylic acid anhydride represented by the formula ##STR1## with an alkali metal cyanide and an alkali metal borohydride.
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