Jeffrey A Sullivan

US Patent:

8609885, Dec 17, 2013

Filed:

Oct 19, 2011

Appl. No.:

13/880438

Inventors:

Adam G. Malofsky - Loveland OH, US
Tanmoy Dey - Stamford CT, US
Jeffrey M. Sullivan - Goshen OH, US
Yangbin Chen - Lima NY, US
Stanley C. Wojciak - New Britain CT, US
Bernard M. Malofsky - Bloomfield CT, US

Assignee:

Bioformix Inc. - Loveland OH

International Classification:

C07C 69/34

US Classification:

560190

Abstract:

The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e. g. , improved cure speed, retention of cure speed, improved shelf-life and/or stability).

US Patent:

20200317827, Oct 8, 2020

Filed:

Jul 13, 2018

Appl. No.:

16/629727

Inventors:

- Loveland OH, US
Anushree Deshpande - Loveland OH, US
Aniruddha Palsule - Cincinnati OH, US
Jeffrey M. Sullivan - Cincinnati OH, US

International Classification:

C08F 2/50
C08F 222/14
C08F 220/18
B05D 3/06
C08K 5/56
C08K 5/357
C08K 5/45
C08K 5/17
C08K 5/55

Abstract:

A method including forming a formulation by contacting one or more photoinitiators with a composition including one or more 1, 1-disubstituted alkene compounds having a purity of about 85 mole percent or more based on total weight of the 1, 1-disubsituted alkene compounds; and exposing the formulation to ultraviolet radiation for initiating free radical polymerization, anionic polymerization, or both, to cure the formulation to form a non-tacky surface. The teachings also contemplate a polymer prepared according to the methods as disclosed.

US Patent:

20190352481, Nov 21, 2019

Filed:

Aug 5, 2019

Appl. No.:

16/531285

Inventors:

- Cincinnati OH, US
Jeffrey Sullivan - Goshen OH, US
Nathan Eckert - Loveland OH, US

International Classification:

C08J 9/00
C08G 18/54
C08G 18/16
C08G 18/20
C08G 18/40
C08G 18/22
C08G 18/48
C08G 18/76
C07F 5/00
C08G 18/42

Abstract:

A class of alkanol amine ligands reacted with bismuth carboxylates lends unique curability properties to isocyanate and polyols for production of polyurethane for CASE applications, including growing demand for polyurethane spray-foam. The amino-alcohol ligand, when associated with bismuth neodecanoate, offers improved moisture and solvent resistance during B-side (polyol) storage, cure rates analogous to tin-based curatives, and overall good final physical properties of the cured polyurethane.

US Patent:

20190315892, Oct 17, 2019

Filed:

Jun 27, 2019

Appl. No.:

16/455040

Inventors:

- Loveland OH, US
Adam G. Malofsky - Loveland OH, US
Tanmoy Dey - Willington CT, US
Jeffrey M. Sullivan - Cincinnati OH, US

International Classification:

C08F 20/28
C08F 24/00
C07C 67/333
C07D 333/24
C09D 129/12
C08F 128/06
C08F 116/36
C07D 333/22
C09D 141/00
C07D 307/46
C09J 133/06
C08F 20/68
C07C 67/343
C08F 20/14
C09D 4/00
C09J 4/00
C08K 3/013
C08K 5/00
C07C 67/30
C07C 49/80
C09J 133/16
C09J 135/02
C09D 135/02
C09D 133/16
C09D 133/14
C08F 20/30
C07C 69/738
C08F 28/06
C08F 222/14
C08L 35/02
C08L 33/16
C08L 33/14
C08L 21/00
C08F 22/20
C08F 20/38
C07D 307/54
C09J 133/14
C07C 45/75
C07C 49/798
C07C 49/796
C07C 49/794
C07C 67/03
C07C 69/604

Abstract:

The present teachings are directed at 1,1-di substituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

US Patent:

20190153272, May 23, 2019

Filed:

Jan 21, 2019

Appl. No.:

16/253006

Inventors:

- Loveland OH, US
Alexander R. Holzer - Cincinnati OH, US
Aniruddha Sudhir Palsule - Cincinnati OH, US
Jeffrey M. Sullivan - Goshen OH, US

International Classification:

C09J 135/02
B01J 19/18
C08F 2/30
C08F 22/10
C08J 3/07
B01J 19/10
C08F 2/26
C08F 122/14
C09D 7/63
C09D 135/02
C09J 11/06
C09J 11/08
C09D 7/65
C08F 267/06

Abstract:

Disclosed is a block copolymer having a first polymer block including a first primary monomer that is a 1,1-disubstituted alkene compound, wherein the first primary monomer is present at a concentration of about 50 weight percent or more, based on the total weight of the first polymer block, the first polymer block covalently bonded to a second polymer block including a second primary monomer different from the first primary monomer, wherein the second primary monomer is present at a concentration of about 50 weight percent or more, based on the total weight of the second polymer block. Also disclosed is a polymer comprising at least one monomer of a 1,1-disubstituted alkene compound having a weight average molecular weight of about 3000 daltons or more, wherein the polymer is substantially free of a melting temperature and is substantially free of a glass transition temperature of about 15 C. or more.

US Patent:

20170355789, Dec 14, 2017

Filed:

Jul 27, 2017

Appl. No.:

15/661893

Inventors:

- LOVELAND OH, US
Adam G. Malofsky - Loveland OH, US
Tanmoy Dey - Willington CT, US
Jeffrey M. Sullivan - Goshen OH, US

International Classification:

C08F 20/28
C09D 135/02
C07C 67/30
C08L 33/14
C08F 24/00
C08F 20/68
C07C 69/604
C09J 133/16
C07C 49/794
C09D 133/16
C08F 20/38
C07C 49/80
C08F 20/30
C07D 307/54
C08K 3/00
C08K 5/00
C08F 128/06
C07C 49/798
C07D 333/22
C07C 49/796
C09J 133/06
C07C 69/738
C07C 67/03
C09J 133/14
C07C 45/75
C08F 28/06
C09D 141/00
C09D 129/12
C08F 116/36
C08L 21/00
C08F 22/20
C07D 307/46
C08L 33/16
C08L 35/02
C09J 135/02
C07D 333/24
C09D 133/14
C08F 222/14
C08F 222/10

Abstract:

The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

US Patent:

20170349700, Dec 7, 2017

Filed:

May 11, 2017

Appl. No.:

15/592829

Inventors:

- Loveland OH, US
Jeffrey M. Sullivan - Goshen OH, US
Kshitij K. Parab - Loveland OH, US
Ami Doshi - Loveland OH, US
Alexander R. Holzer - Loveland OH, US
Matthew Reilman - Cincinnati OH, US

International Classification:

C08G 63/16
B32B 27/36
C08G 63/87
C12P 7/62

Abstract:

Functionalized compounds including residues of one or more 1,1-disubstituted alkene compounds. Preferably the functionalized compound includes the residue of two or more 1,1-disubstituted alkene compounds, which are spaced apart. The functionalized compound may be produced by a transesterification reaction. The functionalized compounds may be employed in a polymerizable composition and may be used to prepare new polymers, (for example by reacting the alkene group).

US Patent:

20170349702, Dec 7, 2017

Filed:

Mar 29, 2017

Appl. No.:

15/472379

Inventors:

- Loveland OH, US
Jeffrey M. Sullivan - Goshen OH, US
Kshitij K. Parab - Loveland OH, US
Elliott King - Milford OH, US
William Barrett - Bethel OH, US

International Classification:

C08G 63/60
C07C 69/593
C08G 64/42
C12P 7/62

Abstract:

Disclosed are compositions comprising polyester macromers containing in one or more chains the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes, and optionally one or more dihydrocarbyl dicarboxylates, and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols. The chains may contain the residue of the one or more diols and one or more diesters comprising one or more diesters 1,1-diester-1 alkenes and optionally one or more dihydrocarbyl dicarboxylates randomly disposed along the chains. Disclosed are methods of preparing the polyester macromers and incorporating them in a variety of polyester containing compositions such as coatings and films.

Address:

2403 Stillwell Beckett Rd, Hamilton, OH 45013

VIN:

JHLRE48757C105985

Make:

HONDA

Model:

CR-V

Year:

2007