A two-stage hydrotreating process comprises the steps of (1) contacting a liquid hydrocarbon-containing feed stream, which contains nickel, vanadium and Ramsbottom carbon residue, with hydrogen and a solid inorganic refractory material (preferably alumina) for at least partial removal of Ni and V, and then (2) hydrovisbreaking the intermediate product stream from step (1). Preferably, step (2) is carried out in the presence of at least one decomposable compound of a metal, preferably a molybdenum dithiophosphate.
Hydrovisbreaking Process For Hydrocarbon Containing Feed Streams
Jerald A. Howell - Bartlesville OK Donald C. Tabler - Bartlesville OK Thomas Davis - Bartlesville OK Simon G. Kukes - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10G 4702 C10G 4704
US Classification:
208112
Abstract:
At least one decomposable molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum compound is then contacted in a hydrovisbreaking process with hydrogen under suitable hydrovisbreaking conditions.
Hydrovisbreaking Process For Hydrocarbon Containing Feed Streams
Jerald A. Howell - Bartlesville OK Simon G. Kukes - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10G 4504 C10G 4560 C10G 4702 C10G 4904
US Classification:
208108
Abstract:
At least one decomposable molybdenum additive selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum additive is then contacted in a hydrovisbreaking process with hydrogen under suitable hydrovisbreaking conditions.
Hydrofining Process For Hydrocarbon Containing Feed Streams
Simon G. Kukes - Bartlesville OK Robert J. Hogan - Bartlesville OK Daniel M. Coombs - Bartlesville OK Jerald A. Howell - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10G 4506
US Classification:
208251H
Abstract:
At least one decomposable compound selected from the group consisting of compounds of the metals of Group IIB and Group IIIB of the Periodic Table is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.
Mixture Of A Molybdenum Carboxylate And A Molybdenum Dithiophosphate Or A Molybdenum Dithiocarbamate For Use In A Hydrovisbreaking Process
Jerald A. Howell - Bartlesville OK Simon G. Kukes - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
B01J 3104 B01J 3112
US Classification:
502167
Abstract:
A decomposable molybdenum compound selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is disclosed. The decomposable molybdenum compound may be added, in a hydrovisbreaking process, to a hydrocarbon-containing feed stream prior to contacting the feed stream with hydrogen under suitable hydrovisbreaking conditions.
Simon G. Kukes - Bartlesville OK Jerald A. Howell - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10G 4504
US Classification:
208108
Abstract:
A hydrotreating (hydrovisbreaking) process comprises the step of contacting under suitable conditions (A) a substantially liquid hydrocarbon-containing feed stream containing more than 0. 1 weight-% Ramsbottom carbon residue, (B) a hydrogen-containing gas and (C) a liquid catalyst composition, which has been prepared by mixing (a) water, (b) at least one alkali metal sulfide or hydrogen sulfide or ammonium sulfide or hydrogen sulfide and (c) at least one molybdenum-oxygen compound, wherein the atomic ratio of S:Mo in this liquid catalyst composition is in the range of from about 0. 6:1 to about 3. 0:1, preferably from about 0. 8:1 to 2. 3:1. Preferably, (b) is (NH. sub. 4). sub. 2 S and (c) is MoO. sub. 3.
Alden E. Beckworth - Bartlesville OK Jerald A. Howell - Bartlesville OK Donald C. Tabler - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10G 1700 C10G 912 C10G 916 C10M 1100
US Classification:
208251R
Abstract:
In a process for producing an essentially ash-free oil stock from a lubricating oil containing ash forming components comprising reacting the oil with an aqueous ammonium salt capable of reacting with the ash-containing components and heating the thus treated oil at a temperature in the range of about 300. degree. C. to about 420. degree. C. to increase the amount of the ash-forming components removed, the improvement comprising not exposing the oil to a temperature greater than 200. degree. C. before the oil is passed into a large volume of the oil already at a temperature in the range of about 300. degree. C. to about 400. degree. C.
Upgrading Fuel Fractions In A Re-Refined Oil Process
Donald C. Tabler - Bartlesville OK Jerald A. Howell - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C10M 1100
US Classification:
208182
Abstract:
In a process for the re-refinement of used lubricating oil containing fuel fraction, an upgraded fuel fraction is provided by combining fuel fraction with demetallized lubricating oil prior to the hydrotreatment stage.
Victoria Shipley (1971-1971), Bryan Dickinson (1979-1983), Mark Jones (1972-1976), Jason Sobol (2000-2002), Jerald Howell (1968-1972), Susan Schmidt (1965-1969)
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