Duane S. Treybig - Lake Jackson TX John M. Motes - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C07D24308
US Classification:
540492
Abstract:
A process for the preparation of 4-(2-hydroxyalkyl)-2-piperazinones and their substituted derivatives comprising reacting an N-hydroxyalkylalkylenediamine, e. g. 2-[(2-aminoethyl)amino]ethanol, or a hydrocarbyl substituted derivative thereof with an. alpha. ,. beta. -dicarbonyl compound, e. g. glyoxal, an alkyl-substituted derivative of glyoxal or a glyoxal equivalent. Certain hexahydro-4-(hydroxyalkyl)-2H-1,4-diazepin-2-ones have been made which are new compounds.
Aziridine Complexes Isomerize To Form Chelated Dimers
Metal salt complexes of aziridine and 2-alkylaziridines in solution isomerize at temperatures between 20. degree. -70. degree. C. to form aziridine dimer chelates. The chelates are biologically active compounds and are chemical intermediates in the preparation of free aziridine dimers.
Preparation Of Hydroxyalkylpiperazinones By Reacting A 2,3-Dihydroxy-1,4-Dioxane With A Hydroalkyldiamine
Duane S. Treybig - Lake Jackson TX John M. Motes - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C07D24108
US Classification:
544384
Abstract:
A process for the preparation of 4-(2-hydroxyalkyl)-2-piperazinones and their substituted derivatives comprising reacting an N-hydroxyalkylalkylenediamine, e. g. 2-[(2-aminoethyl)amino]ethanol, or a hydrocarbyl substituted derivative thereof with an. alpha. ,. beta. -dicarbonyl compound, e. g. glyoxal, an alkyl-substituted derivative of glyoxal or a glyoxal equivalent. Certain hexahydro-4-(hydroxyalkyl)-2H-1,4-diazepin-2-ones have been made which are new compounds.
Stabilization Of Polyisocyanates Against Discoloration
John L. Nafziger - Lake Jackson TX John M. Motes - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C07C119042
US Classification:
260453SP
Abstract:
Polyisocyanates are stabilized against discoloration by the addition of certain hindered phenols such as o,o-di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyl benzyl phosphonate.
Sulfur Dioxide Removal From Gas Streams Using Hydroxyalkyl Substituted Piperazinones
Duane S. Treybig - Lake Jackson TX James L. Potter - Lake Jackson TX Mark B. Jones - Lake Jackson TX John M. Motes - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C01B 1700 B01D 1900
US Classification:
423243
Abstract:
A method of removing SO. sub. 2 from a gas stream containing the same by absorbing the SO. sub. 2 in an aqueous solution containing a 4-(2-hydroxyalkyl)-2-piperazinone compound or an alkyl or aryl substituted derivative thereof. These compounds provide an absorbent solution which is less subject to loss during the regeneration step and yet effectively remove the SO. sub. 2 from the gas stream without interference from other associated gases.