The present invention provides methods and apparatus for analysis and monitoring of electrolyte bath composition. Based on analysis results, the invention controls electrolyte bath composition and plating hardware. Thus, the invention provides control of electroplating processes based on plating bath composition data. The invention accomplishes this by incorporating accurate bath component analysis data into a feedback control mechanism for electroplating. Bath electrolyte is treated and analyzed in a flow-through system in order to identify plating bath component concentrations and based on the results, the plating bath formulation and plating process are controlled.
An electroplating apparatus prevents anode-mediated degradation of electrolyte additives by creating a mechanism for maintaining separate anolyte and catholyte and preventing mixing thereof within a plating chamber. The separation is accomplished by interposing a porous chemical transport barrier between the anode and cathode. The transport barrier limits the chemical transport (via diffusion and/or convection) of all species but allows migration of ionic species (and hence passage of current) during application of sufficiently large electric fields within electrolyte.
Method For Potential Controlled Electroplating Of Fine Patterns On Semiconductor Wafers
Steven T. Mayer - Clackamas OR Jonathan Reid - Sherwood OR Robert Contolini - Clackamas OR
Assignee:
Novellus Systems, Inc. - San Jose CA
International Classification:
C25D 2112
US Classification:
205 81, 205 87, 205102, 205103, 205104
Abstract:
Controlled-potential electroplating provides an effective method of electroplating metals onto the surfaces of high aspect ratio recessed features of integrated circuit devices. Methods are provided to mitigate corrosion of a metal seed layer on recessed features due to contact of the seed layer with an electrolyte solution. The potential can also be controlled to provide conformal plating over the seed layer and bottom-up filling of the recessed features. For each of these processes, a constant cathodic voltage, pulsed cathodic voltage, or ramped cathodic voltage can be used. An apparatus for controlled-potential electroplating includes a reference electrode placed near the surface to be plated and at least one cathode sense lead to measure the potential at points on the circumference of the integrated circuit structure.
Methods And Apparatus For Controlled-Angle Wafer Immersion
Jonathan D. Reid - Sherwood OR Steven T. Mayer - Lake Oswego OR Seshasayee Varadarajan - Wilsonville OR David C. Smith - Lake Oswego OR Evan E. Patton - Portland OR Dinesh S. Kalakkad - Portland OR Gary Lind - Penn Valley CA
Assignee:
Novellus Systems, Inc. - San Jose CA
International Classification:
C25D 500
US Classification:
205137, 205143, 205149
Abstract:
The orientation of a wafer with respect to the surface of an electrolyte is controlled during an electroplating process. The wafer is delivered to an electrolyte bath along a trajectory normal to the surface of the electrolyte. Along this trajectory, the wafer is angled before entry into the electrolyte for angled immersion. A wafer can be plated in an angled orientation or not, depending on what is optimal for a given situation. Also, in some designs, the wafers orientation can be adjusted actively during immersion or during electroplating, providing flexibility in various electroplating scenarios.
Apparatus For Potential Controlled Electroplating Of Fine Patterns On Semiconductor Wafers
Steven T. Mayer - Lake Oswego OR Jonathan Reid - Sherwood OR Robert Contolini - Lake Oswego OR
Assignee:
Novellus Systems, Inc. - San Jose CA
International Classification:
B23H 302
US Classification:
2042299, 2042298, 2042307, 2042971, 20429714
Abstract:
Controlled-potential electroplating provides an effective method of electroplating metals onto the surfaces of high aspect ratio recessed features of integrated circuit devices. Methods are provided to mitigate corrosion of a metal seed layer on recessed features due to contact of the seed layer with an electrolyte solution. The potential can also be controlled to provide conformal plating over the seed layer and bottom-up filling of the recessed features. For each of these processes, a constant cathodic voltage, pulsed cathodic voltage, or ramped cathodic voltage can be used. An apparatus for controlled-potential electroplating includes a reference electrode placed near the surface to be plated and at least one cathode sense lead to measure the potential at points on the circumference of the integrated circuit structure.
An anode includes an anode cup, a membrane and ion source material, the anode cup and membrane forming an enclosure in which the ion source material is located. The anode cup includes a base section having a central aperture and the membrane also has a central aperture. A jet is passed through the central apertures of the base section of the anode cup and through the membrane allowing plating solution to be directed at the center of a wafer being electroplated.
Method For Electrochemical Planarization Of Metal Surfaces
Methods and apparatus are used for electrochemical planarization of an electrically conductive material surface with varying topography from a partially fabricated integrated circuit, in which protruding regions of the conductive material are removed more quickly than recessed regions to thereby increase the planarity of the conductive material surface. This is accomplished by using dissolution electrochemistry. The partially fabricated integrated circuit is used as the anode in an electrochemical cell, with the anode and cathode active surfaces positioned in very close proximity. By using highly resistive electrolyte and moving the anode and cathode progressively closer during electrochemical dissolution, the electrically conductive material surface is effectively planarized.
Electroless Copper Deposition Method For Preparing Copper Seed Layers
Tatyana N. Andryuschenko - Portland OR Jonathan D. Reid - Sherwood OR Steven T. Mayer - Lake Oswego OR Eric G. Webb - Salem OR
Assignee:
Novellus Systems, Inc. - San Jose CA
International Classification:
H01L 2166
US Classification:
438 17, 438687
Abstract:
Disclosed is a procedure for deposition of a thin and relatively continuous electroless copper film on the substrate of sub-micron integrated circuit features. The electroless copper film is deposited onto a previously deposited PVD copper film, which may be discontinuous. The continuous film formed by electroless deposition allows for sufficient filling of the sub-micron integrated circuit features by electrodeposition. The electroless bath employed to form the continuous electroless copper film may be composed of a reducing agent, a complexing agent, a source of copper ions, a pH adjuster, and optionally one or more surfactants and/or stabilizers. In one example, the reducing agent contains an aldehyde moiety.
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Making an instrument that could provide such information would turn into a six-year slog. Initially, Haddrell tried to adapt a technology known as optical tweezers, developed by a colleague of his at Bristol named Jonathan Reid. It uses lasers to trap particles in a microscope for extended periods
Date: Jun 04, 2024
Category: Health
Source: Google
Scientists discover critical factors that determine the survival of airborne viruses
Jonathan Reid, Director of Bristol Aerosol Research Centre and Professor of Physical Chemistry in the School of Chemistry at the University of Bristol, and one of the corresponding authors, said, "There are numerous factors that affect the transmission of airborne viruses, and these are often confou
Date: Jun 20, 2023
Category: Science
Source: Google
Vampyr to add two new difficulty settings later this summer
asize combat, making it easier for players to wend their way through the games story if that is what they find most appealing. Vampyr was critiqued for difficulty spikes in the main game when it launched, and so this should smooth those out for those intrigued by the tale of Dr. Jonathan Reid.
Date: Jul 28, 2018
Category: Headlines
Source: Google
Vampyr Summer Update to Bring an Easier Story Mode and a More Challenging Hard Mode
If you're currently having a hard time with Vampyr, or if the hard mode gets too challenging later this summer, head over to our Vampyr walkthrough. If you'd just like some tips and tricks for playing as Dr. Jonathan Reid, well, we have you covered there too.