A method for reducing aldehydes in an acetic acid production process is disclosed. The acetic acid is produced by reacting methanol and carbon monoxide in the presence of a carbonylation catalyst. The method comprises reacting an aldehyde-containing stream with an alcohol to form an acetal-containing stream. An acetal-enriched stream is separated from the acetal-containing stream and then hydrolyzed to form a hydrolysis mixture comprising the alcohol and the aldehydes. The alcohol is isolated from the hydrolysis mixture and used to react with the aldehyde-containing stream to form the acetal-containing stream. The invention reduces aldehydes in the acetic acid produced.
Michael E. Fitzpatrick - League City TX, US Miraj S. Patel - Sugar Land TX, US
International Classification:
C07C 51/44 C07C 51/12
US Classification:
562519, 203 67, 203 87
Abstract:
The phase separation in the decanter of a process for producing acetic acid by carbonylating methanol in the presence of a catalyst under low water-high acid conditions is facilitated and expedited by forming a liquid mixture (D) which has a water content of at most 10% by weight, based on the weight of the liquid mixture, an acetic acid content of at least 10% by weight, based on the weight of the liquid mixture, and a weight ratio of methyl iodide to methyl acetate of at least 1.5:1, and partitioning the liquid mixture at a temperature of from 0 to 35 C.
John D. Hearn - Beach City TX, US Michael E. Fitzpatrick - League City TX, US Miraj S. Patel - Sugar Land TX, US
Assignee:
Lyondell Chemical Technology, LP. - Houston TX
International Classification:
C07C 51/44
US Classification:
568909
Abstract:
The phase separation in the decanter of a process for producing acetic acid by carbonylating methanol in the presence of a catalyst under low water-high acid conditions is improved by forming a liquid mixture (D) which has a water content of at most 20% by weight, based on the weight of the liquid mixture, and a weight ratio of acetic acid to water of at least 1:1, and partitioning the liquid mixture by providing for an alkane(s) content of D of from 0.1 to 15% by weight, based on the weight of D, to obtain a light, aqueous phase and a heavy, organic phase.
- Houston TX, US Sanjeev Deshpande - Sugar Land TX, US Michael E. Fitzpatrick - Nutley NJ, US Noel C. Hallinan - Loveland OH, US John D. Hearn - Beach City TX, US
Assignee:
LyondellBasell Acetyls, LLC - Houston TX
International Classification:
C07C 51/12 B01J 31/02 B01J 31/10 C07C 51/44
Abstract:
The present technology relates to the production and recovery of acetic acid. The recovery processes may include providing a first process stream including acetic acid and greater than 250 ppm of propionic acid; separating at least a portion of the propionic acid from the acetic acid within the first process stream to provide an acetic acid stream including acetic acid and less than 250 ppm of propionic acid and a bottoms stream including propionic acid and acetic acid; reacting the bottoms stream to form a product stream including components of respectively lower boiling points than corresponding components in the bottoms stream; and separating components of the product stream to form an overhead stream including one or more acetates and a bottoms stream including one or more propionates.
Dr. Fitzpatrick graduated from the Philadelphia College of Osteopathic Medicine in 2002. He works in Greencastle, PA and specializes in Family Medicine and Osteopathic Manipulative Medicine.
Dr. Fitzpatrick graduated from the University of Kentucky College of Medicine in 1983. He works in Elizabethtown, KY and specializes in Family Medicine.
Dr. Fitzpatrick graduated from the University of Toledo College of Medicine in 1984. He works in Tiffin, OH and specializes in Emergency Medicine. Dr. Fitzpatrick is affiliated with Mercy Tiffin Hospital.
Dr. Fitzpatrick graduated from the Virginia Commonwealth University SOM in 1994. He works in Williamsburg, VA and specializes in Family Medicine. Dr. Fitzpatrick is affiliated with Sentara Williamsburg Regional Medical Center.
Oakwood Women's CentreOakwood Womens Centre 511 Oakwood Blvd STE 301, Round Rock, TX 78681 5122443698 (phone), 5122440214 (fax)
Education:
Medical School University of Texas Medical Branch at Galveston Graduated: 1983
Procedures:
Cystoscopy Cesarean Section (C-Section) Delivery After Previous Caesarean Section Hysterectomy Tubal Surgery Vaccine Administration Vaginal Delivery Vaginal Repair
Conditions:
Breast Disorders Candidiasis of Vulva and Vagina Conditions of Pregnancy and Delivery Diabetes Mellitus Complicating Pregnancy or Birth Menopausal and Postmenopausal Disorders
Languages:
English Spanish
Description:
Dr. Fitzpatrick graduated from the University of Texas Medical Branch at Galveston in 1983. He works in Round Rock, TX and specializes in Gynecology. Dr. Fitzpatrick is affiliated with St Davids Round Rock Medical Center.
South Orange County Orthopedics 26730 Crown Vly Pkwy STE 200, Mission Viejo, CA 92691 9493642154 (phone)
Education:
Medical School Thomas Jefferson University, Jefferson Medical College Graduated: 1993
Conditions:
Internal Derangement of Knee Internal Derangement of Knee Cartilage Internal Derangement of Knee Ligaments Lateral Epicondylitis Plantar Fascitis
Languages:
English Korean Spanish
Description:
Dr. Fitzpatrick graduated from the Thomas Jefferson University, Jefferson Medical College in 1993. He works in Mission Viejo, CA and specializes in Orthopaedic Surgery and Orthopedic Sports Medicine. Dr. Fitzpatrick is affiliated with Hoag Hospital Irvine and Mission Hospital.
Geisinger Medical GroupGeisinger Medical Center Emergency Medicine 100 N Academy Ave, Danville, PA 17822 5702716812 (phone), 5702716507 (fax)
Education:
Medical School Thomas Jefferson University, Jefferson Medical College Graduated: 1992
Languages:
English
Description:
Dr. Fitzpatrick graduated from the Thomas Jefferson University, Jefferson Medical College in 1992. He works in Danville, PA and specializes in Emergency Medicine. Dr. Fitzpatrick is affiliated with Geisinger Medical Center, Geisinger Wyoming Valley Hospital and Geisinger-Shamokin Area Community Hospital.
Medical School Indiana University School of Medicine Graduated: 1989
Languages:
English
Description:
Dr. Fitzpatrick graduated from the Indiana University School of Medicine in 1989. He works in Jeffersonville, IN and specializes in Anesthesiology. Dr. Fitzpatrick is affiliated with Clark Memorial Hospital.
Please follow my project to create a new design for the Imperial State Crown. Its not my intention to copy the crown exactly more to create the feeling that the crown gave me. Last year when I visite...
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Imperial State Crown
Michael Fitzpatrick
Work:
Fitness Australia - Relationship Manager
Michael Fitzpatrick
Education:
Grinnell College
Michael Fitzpatrick
Education:
Pennsylvania State University - Agri-Business Managment
Michael Fitzpatrick
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Venezuela has avoided formal OAS condemnation thanks to the support of the bloc of Caribbean nations that have benefited from its subsidized oil and development programs for years, said Michael Fitzpatrick, deputy assistant secretary in the U.S. State Departments Bureau of Western Hemisphere Affa
Date: May 15, 2018
Category: World
Source: Google
U.S. May Consider New Venezuela Sanctions as Crisis Deepens
The Venezuelan government has decided once again to change the rules of the game in mid-play, Michael Fitzpatrick, U.S. deputy assistant secretary for Western Hemisphere Affairs, said Tuesday on a reporter call. The actions that were taken yesterday may well give us new reasons for considering ad
Date: May 02, 2017
Category: World
Source: Google
As president calls for new constitution, Venezuela veers once again toward political chaos
On Tuesday, Michael Fitzpatrick, the State Department deputy assistant secretary for the Western Hemisphere, told reporters in Washington that the U.S. will talk to other countries in the region to consider imposing new sanctions on Venezuela in light of Maduros recent crackdown on dissent.
In Washington, US state department spokesman Michael Fitzpatrick told reporters: "We have deep concerns about the motivation for this constituent assembly which overrides the will of the Venezuelan people and further erodes Venezuelan democracy.
Date: May 02, 2017
Category: World
Source: Google
'Hamilton' actress, Luke Bryan reflect on Super Bowl moments
The cool thing for us is that it kind of became one of those unofficial songs of the NFL this year because I think it started when the Dallas Cowboys cheerleaders did a routine to it, and every other teams cheerleading squad did a routine, singer Michael Fitzpatrick said. Weve been all over NFL
"I wasn't dreaming, can't believe/I woke up to my woman kissing Santa, not me," singer Michael Fitzpatrick laments in blue-eyed vocals that bring to mind Darryl Hall. "Before I could reach him, even think/He swooped away my honey out the chimney sweep."
Date: Dec 23, 2016
Category: Entertainment
Source: Google
OAS head calls for recall of Maduro to restore democracy in spiraling Venezuela
Dialogue is important, said Michael Fitzpatrick, the U.S. representative to the OAS. However, we cannot allow it be excuse for inaction. The Venezuelan people cannot afford delays for finding solutions to the problems they face.
Date: Jun 23, 2016
Category: World
Source: Google
Gun violence not a mental health issue, experts say, pointing to 'anger,' suicides
"Recent tragedies have focused attention on the fact that most people with serious mental illness do not have access to mental health treatment," NAMI executive director Michael Fitzpatrick said in an open letter in 2013.