Abstract:
Release compositions include (a) from zero to about 30 parts by weight of a polymer selected from the group consisting of wherein R , R , R , R , R , R , R , and R are each independently selected from an alkyl group, an alkenyl group, an aryl group, and an aralkyl group, such that at least one of R and R is an alkenyl group, l, m, and n are each independently an integer so long as the polymer contains greater than 3 mol % vinyl-containing siloxane groups; a (vinyl siloxy)(siloxy)-modified silica having a vinyl content of at least about 0. 4 vinyl equivalent/kg; and a combination thereof; (b) more than about 20 parts by weight of a polymer having the formula wherein R , R , R , R , R , R , R , and R are each independently selected from an alkyl group, an alkenyl group, an aryl group, and an aralkyl group, such that at least two of R , R , R , R , R , R , R , and R are alkenyl groups, p, q, and r are each independently integers so long as the polymer has less than 3 mol % vinyl-containing siloxane groups; and (c) up to about 20 parts by weight of a cross-linking agent of the formula wherein R , R , R , R , R , and R are each independently selected from hydrogen, an alkyl group, an aryl group, and an aralkyl group, X is O, or a divalent organic linking group, and s and t are independently integers so long as there are at least two functional groups capable of cross-linking per molecule.