A glass sheet has an electrically conductive film having a sheet resistance in the range of 9.5 to 14.0 ohms/square; an emissivity in the range of 0.14 to 017 and an absorption coefficient of greater than 1.5×10cmin the wavelength range of 400-1100 nanometers, and a surface roughness of less than 15 nanometers Root Means Square. A glass sheet of another embodiment of the invention has an electrically conductive film having a phosphorous-fluorine doped tin oxide pyrolytically deposited film on the surface of the glass sheet, wherein the ratio of phosphorous precursor to tin precursor is in the range of greater than 0-0.4. The coated glass sheets of the invention can be used in the manufacture of multi sheet insulating units, OLEDs and solar cells.
Ronald D. Goodman - Toledo OH Peter J. Tausch - Perrysburg OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
C23C 1608 C23C 1630 B05D 506 C03C 1734
US Classification:
427166
Abstract:
Coated glass articles, particularly useful as vehicle or architectural glazings, are prepared by a chemical vapor deposition process in which glass is coated with a first layer of titanium nitride, a second layer of a silicon complex, and optionally, a third layer of a metal oxide.
Method For Producing An Electrically Heated Window Assembly And Resulting Article
Robert B. Nikodem - Toledo OH Peter J. Tausch - Perrysburg OH Ronald D. Goodman - Toledo OH Robert M. Felt - Toledo OH Michael J. Grogan - Toledo OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
H05B 316
US Classification:
219543
Abstract:
A method for forming a vehicle window assembly includes applying a band of an opaque ceramic enamel material to a predetermined peripheral portion of a sheet of relatively flat glass, and heating the glass to a prefire temperature to fuse the opaque material to the glass. An electrically conductive material is applied to the band in a predetermined pattern to form a pair of bus bars typically along the top and bottom edges of the sheet of glass. The glass is again heated to fire the bus bar material and soften the glass for bending into a desired window shape. A mask is applied to the bus bars for later connection of electrical leads and the sheet of glass is washed prior to the next operation. An electrically conductive film is applied to the second surface of the sheet of glass and electrically connected to the bus bars. The sheet of glass is laminated to a sheet of plastic material which covers the electrically conductive film and, typically, the plastic sheet is laminated to a second sheet of glass which has been preformed, i. e.
Ronald D. Goodman - Toledo OH William M. Greenberg - Oregon OH Peter J. Tausch - Perrysburg OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
B05D 506
US Classification:
427166
Abstract:
This disclosure is directed to a heat reflective glazing including a glass sheet having two generally planar parallel surfaces or sides with a multilayer coating on one of the side, and a method of producing such glazing. The side of the glass sheet having the multilayer coating thereon is designated as the film or coated side while the other side is designated as the glass side of the glass sheet. The multilayer coating comprises a first silicon-containing coating formed directly on the glass surface, a titanium nitride-containing coating overlying the first coating, a second silicon-containing coating covering the titanium nitride-containing coating, and an optional abrasion resistant coating, e. g. , comprising tin oxide, on the second silicon-containing coating. The process for producing the coatings is a chemical vapor deposition process preferably carried out during the production of glass by the float process.
Ronald D. Goodman - Toledo OH William M. Greenberg - Oregon OH Peter J. Tausch - Perrysburg OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
B32B 900
US Classification:
428426
Abstract:
This disclosure is directed to a heat reflective glazing including a glass sheet having two generally planar parallel surfaces or sides with a multilayer coating on one of the side, and a method of producing such glazing. The side of the glass sheet having the multilayer coating thereon is designated as the film or coated side while the other side is designated as the glass side of the glass sheet. The multilayer coating comprises a first silicon-containing coating formed directly on the glass surface, a titanium nitride-containing coating overlying the first coating, a second silicon-containing coating covering the titanium nitride-containing coating, and an optional abrasion resistant coating, e. g. , comprising tin oxide, on the second silicon-containing coating. The process for producing the coatings is a chemical vapor deposition process preferably carried out during the production of glass by the float process.
Sputtered Multi-Layer Color Compatible Solar Control Coating
Peter J. Tausch - Perrysburg OH Ronald D. Goodman - Toledo OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
H05B 310
US Classification:
219547
Abstract:
A glazing unit having incorporated therewith a solar control filter, comprising combinations of layers of transparent films adhered to the surface of a transparent glass sheet. A protective covering is provided over the coating stack. The coating stack includes at least three layers of zinc oxide and at least two layers of silver deposited alternately one upon another, with each layer of silver between two layers of zinc oxide. The glazing unit exhibits color compatibility in environments, where normally employed. The electrically conducting silver layers enable the coating stack to optionally be utilized as a defogging and deicing system for the unit.
Ronald D. Goodman - Toledo OH Peter J. Tausch - Perrysburg OH
Assignee:
Libbey-Owens-Ford Co. - Toledo OH
International Classification:
B32B 1706
US Classification:
428428
Abstract:
Coated class articles, particularly useful as vehicle or architectural glazings, are prepared by a chemical vapor deposition process in which glass is coated with a first layer of titanium nitride, a second layer of a silicon complex, and optionally, a third layer of a metal oxide.
Solar Cell With Selectively Doped Conductive Oxide Layer And Method Of Making The Same
A method of making a coated substrate having a transparent conductive oxide layer with a dopant selectively distributed in the layer includes selectively supplying an oxide precursor material and a dopant precursor material to each coating cell of a multi-cell chemical vapor deposition coater, wherein the amount of dopant material supplied is selected to vary the dopant content versus coating depth in the resultant coating.
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