Coke deposits are removed from particulates by combustion in a regenerator by a process in which air is initially used as the oxidant. The combustion gas is subjected to a separation process to remove nitrogen therefrom, and the remaining carbon dioxide-enriched gas stream is recycled to the regenerator together while substantially pure oxygen is introduced into the regenerator. As the level of carbon dioxide in the system increases, the amount of air being introduced into the regenerator is gradually reduced and, in compensation, the amount of oxygen flowing to the regenerator is gradually increased. Eventually, part or all of the air is replaced by oxygen and carbon dioxide recycle gas, and the level of oxygen and carbon dioxide are regulated to maintain the desired temperature in the regenerator.
Raghu Menon - Medford NJ Ramakrishnan Ramachandran - Allendale NJ Virginia Malik - Linden NJ Martin Bulow - Basking Ridge NJ
Assignee:
The BOC Group, Inc. - New Providence NJ
International Classification:
C07C 256 C07C 712
US Classification:
585717
Abstract:
A hydrocarbon stream is cracked to produce a hot gaseous stream which is compressed and cooled to condense almost all of the hydrocarbons contained in the stream. A noncondensed stream remaining after the condensation step, comprised predominantly of hydrogen and C. sub. 1 to C. sub. 3 hydrocarbons, is subjected to pressure swing adsorption or temperature swing adsorption at an adsorption temperature of about 0. degree. to about 250. degree. C. in a bed of adsorbent which selectively adsorbs ethene and propene, thereby adsorbing substantially all of the ethene and propene from the gas stream. The ethene and/or propene is recovered upon bed regeneration. Higher alkenes are separated from alkanes by various methods.
Fcc Of Nitrogen Containing Hydrocarbons And Catalyst Regeneration
Amos A. Avidan - Yardley PA Mark F. Mathias - Turnersville NJ Raghu K. Menon - Medford NJ Joseph F. Sodomin - Centerville VA Scott A. Stevenson - Newton PA Gerald J. Teitman - Vienna VA
Assignee:
Mobil Oil Corporation - Fairfax VA
International Classification:
C10G 1118 C10G 1105 B01J 3836 B01J 2938
US Classification:
208113
Abstract:
Oxides of nitrogen (NO. sub. x) emissions from an FCC regenerator are reduced by forcing the regenerator to operate between full and partial CO burn mode. Operating with less than 1 mole % O2 and up to 1 or 2% CO in the flue gas creates conditions which oxidize nitrogen compounds in coke on spent catalyst to NOx, and simultaneously convert NOx in the regenerator to nitrogen. A downstream CO boiler can burn this low CO flue gas without producing large amounts of NOx. Most NOx emissions can be eliminated. An apparatus, with the regenerator air:coke ratio controlled by both CO and O2 analyzers monitoring regenerator flue gas, is also disclosed.
Hydrocarbon fluid catalytic cracking (FCC) plants are debottlenecked by subjecting part or all of the wet gas stream leaving the main fractionator overhead receiver to pressure swing adsorption to remove methane and hydrogen from this gas stream prior to its introduction into the wet gas compressor. This allows debottlenecking of the compressor system. It can allow the reduction in pressure in the system back to the catalyst regenerator. The reduction in pressure in the catalyst regenerator makes it possible to increase the rate of regeneration of catalyst. Consequently, the rate of hydrocarbon throughput in the FCC plant can be increased.
Coke is burned in the regenerator vessel of an FCC complex with a combustion medium consisting of a diluent gas, such as air, enriched with oxygen, The regenerator is operated in partial combustion mode and excess oxygen is introduced into the combustion zone of the regenerator. Emission of nitrogen oxides to the atmosphere is reduced.
Hydrocarbon fluid catalytic cracking (FCC) plants are debottlenecked by replacing air feed to the cracking catalyst regenerator with oxygen and carbon dioxide exhaust from the catalyst regenerator and removing methane and hydrogen from the wet gas stream leaving the main fractionator overhead receiver prior to its introduction into a wet gas compressor system. Nitrogen is removed from the exhaust gas and methane and hydrogen are removed from the wet gas in the same pressure swing adsorption (PSA) plant. During air replacement, exhaust gas is processed in the PSA plant and when the desired amount of nitrogen is removed from the exhaust gas, feed of exhaust gas to the PSA plant is terminated and flow of wet gas to the PSA plant is initiated.
Name / Title
Company / Classification
Phones & Addresses
Raghu Menon
RPM2 INC
Resumes
Head Of Hyco Syngas Global Business Unit, President Of Hyco Syngas Operations And Svp, Matheson
Matheson Tnsc
Head of Hyco Syngas Global Business Unit, President of Hyco Syngas Operations and Svp, Matheson
The Linde Group 2007 - May 2015
Head, Business Development, North and South America, Global Bu Tonnage
The Linde Group 1994 - 2006
Various Positions
Imperial Oil 1990 - 1994
Senior Staff Engineer
Education:
Saïd Business School, University of Oxford 2011 - 2011
Columbia Business School 1999 - 1999
Massachusetts Institute of Technology 1985 - 1990
Indian Institute of Technology, Madras 1980 - 1984
Bachelors, Chemical Engineering
Don Bosco Matriculation School 1971 - 1979
Loyola College 1978 - 1979
Don Bosco Matriculation Higher Secondary School - Egmore
University of Oxford
Skills:
Business Development Process Engineering Chemical Engineering Management Leadership Process Simulation Petrochemical Business Strategy Engineering Industrial Gases Market Development Gas Product Development Commercialization Investments Petroleum Polymers Project Management Oil Industry International Business Strategy Business Management