##STR1## where X is 1, 2 or 3; Y is Cl or Br; R. sub. 1 is tert-butyl (t-butyl) and R. sub. 2 is H or lower alkyl of 1 to 4 carbons. The preferred group of compounds is where OH is at the 4 position, R. sub. 1 is at the 3 position and R. sub. 2 is at the 5 position of the phenyl ring. The most preferred compound is where X is 2, R. sub. 1 and R. sub. 2 are both t-butyl at the 3 and 5 positions of the phenyl ring and OH is at the 4 position of the phenyl ring and Y is Br. The compounds are useful as antioxidants and flame retardants.
Thiodipropionoyl Bis(Halo 5-Norbornene 2,3-Dicarboxylic Acid Hydrazide) Additives For Polymers
A compound of the formula (I) ##STR1## Polymer compositions including antioxidants and the compounds or the compound alone are useful as electrical insulation e. g. , for copper cable, as heat shrinkable (heat recoverable) parts or as other plastic parts to improve the retention of mechanical and/or electrical properties of the insulation or parts.
##STR1## where X is 1, 2 or 3; Y is Cl or Br; R. sub. 1 is tert-butyl (t-butyl) and R. sub. 2 is H or lower alkyl of 1 to 4 carbons. The preferred group of compounds is where OH is at the 4 position, R. sub. 1 is at the 3 position and R. sub. 2 is at the 5 position of the phenyl ring. The most preferred compound is where X is 2, R. sub. 1 and R. sub. 2 are both t-butyl at the 3 and 5 positions of the phenyl ring and OH is at the 4 position of the phenyl ring and Y is Br. The compounds are useful as antioxidants and flame retardants.
Hindered Phenolic Norbornane-2,3-Dicarboximides And Stabilized Compositions
##STR1## where X is 1, 2 or 3; Y is Cl or Br; R. sub. 1 is tert-butyl (t-butyl) and R. sub. 2 is H or lower alkyl of 1 to 4 carbons. The preferred group of compounds is where OH is at the 4 position, R. sub. 1 is at the 3 position and R. sub. 2 is at the 5 position of the phenyl ring. The most preferred compound is where X is 2, R. sub. 1 and R. sub. 2 are both t-butyl at the 3 and 5 positions of the phenyl ring and OH is at the 4 position of the phenyl ring and Y is Cl. The compounds are useful as antioxidants and flame retardants.
Thiodipropionoyl Bis (Halo Benzhydrazide) Additives For Polymers
Compounds of the formula (I) ##STR1## where Y is H, Cl or Br with at least one Y always being Cl or Br and X is S or S--S. Polymer compositions including antioxidants and the compounds or the compound alone are useful as electrical insulation e. g. , for copper cable, as heat shrinkable (heat recoverable) parts or as other plastic parts to improve the retention of mechanical and/or electrical properties of the insulation or parts.
Gordon Duncan, Larry Miller, Warren Jones, Robert Jewett, James Hagel, Pat Astorino, Enella Dibben, Barbara Gageby, Willa Janklow, Jim Redman, Evelyn Nissen