Robert A Kay

US Patent:

7799316, Sep 21, 2010

Filed:

Jan 24, 2007

Appl. No.:

11/657315

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C01B 39/04
C01B 39/48

US Classification:

423706, 423702, 423718

Abstract:

A method of manufacturing a molecular sieve of the MCM-22 family, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element, at least one source of alkali metal hydroxide, at least one directing-agent (R), water, and optionally at least one source of ions of trivalent element, said mixture having the following mole composition:.

US Patent:

7816573, Oct 19, 2010

Filed:

Jan 26, 2007

Appl. No.:

11/698533

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US
Christine N. Elia - Bridgewater NJ, US
Frederick Y. Lo - Middlesex NJ, US
David O. Marler - Morris Plains NJ, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C07C 2/66
B01J 29/04
B01J 29/80
C01B 39/00
C01B 39/02

US Classification:

585467, 502 60, 502 67, 423700, 423702, 423706, 423709, 208135

Abstract:

The invention relates to a process for converting hydrocarbons with a catalyst comprising a crystalline molecular sieve composition which is obtainable by crystallizing a pre-formed extrudate mixture in a reactor and, during crystallization, removing excess alkali metal hydroxide from the pre-formed extrudate. The pre-formed extrudate mixture comprises at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X. The reaction mixture has the following mole composition: Y:X=10 to infinity; OH:Y=0. 001 to 2; and M:Y=0. 001 to 2; wherein M is an alkali metal. The amount of water in the mixture is at least sufficient to permit extrusion of said reaction mixture.

US Patent:

7829062, Nov 9, 2010

Filed:

Jan 26, 2007

Appl. No.:

11/698500

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US

Assignee:

ExxonMobil Chemical Patent Inc. - Houston TX

International Classification:

C01B 39/02

US Classification:

423700, 423702, 423706

Abstract:

A method of preparing a crystalline molecular sieve is provided, which method comprises.

US Patent:

7846418, Dec 7, 2010

Filed:

Jan 24, 2007

Appl. No.:

11/657192

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C01B 39/46
B01J 29/06
C10G 47/04

US Classification:

423718, 423706, 423702, 208 46, 20811101, 208135

Abstract:

An MCM-22 family molecular sieve having an X-ray diffraction pattern of the as-synthesized MCM-22 family molecular sieve including d-spacing maxima at 12. 40. 25, 3. 570. 07 and 3. 420. 07 Angstroms and at least one peak between 26. 6 and 29 (2θ). The peak between 26. 6 to 29 (2θ) has a two theta (2θ) of about 26. 9. A method of manufacturing an MCM-22 family molecular sieve, said method comprising the steps of (a) combining at least one silicon source, at least one source of alkali metal hydroxide, at least one directing-agent (R), water, and optionally one aluminum source, to form a mixture having the following mole composition:.

US Patent:

7883686, Feb 8, 2011

Filed:

Jun 28, 2007

Appl. No.:

11/823722

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US
Mohan Kalyanaraman - Media PA, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C01B 39/48
C01B 39/46
C10G 11/05
C10G 47/16
C10G 49/08
C10G 25/03
C07C 7/13

US Classification:

423700, 423705, 423706, 423709, 423718, 20811101, 20811115, 208136, 208143, 208310 Z

Abstract:

This disclosure relates to a crystalline MCM-22 family molecular sieve having a platelet aggregates morphology wherein greater than 50 wt % of the molecular sieve having a crystal diameter greater than 1 μm as measured by the SEM. The crystalline MCM-22 family molecular sieve of this disclosure, wherein the platelet aggregates morphology is rosette habit morphology, or multiple layer plate's morphology.

US Patent:

8003074, Aug 23, 2011

Filed:

Sep 18, 2007

Appl. No.:

11/901490

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Wieslaw J. Roth - Sewell NJ, US
Robert E. Kay - Easton PA, US
Christine N. Elia - Bridgewater NJ, US

Assignee:

ExxonMobil Research and Engineering Company - Annandale NJ

International Classification:

C01B 39/04
C10G 73/42
C10G 49/08

US Classification:

423704, 423708

Abstract:

A process for producing ZSM-48 comprises crystallizing an aqueous reaction mixture comprising at least one source of silica, at least one source of alumina, at least one source of hydroxyl ions, at least one source of diquaternary alkylammonium, R, ions having the formula:(CH)N(CH)N(CH)and optionally ZSM-48 seed crystals, wherein said reaction mixture has a composition including the following molar ratios:.

US Patent:

8017540, Sep 13, 2011

Filed:

Oct 1, 2010

Appl. No.:

12/896065

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C01B 39/02
C01B 39/04
C01B 39/46
C01B 39/48
B01J 29/04
B01J 29/70

US Classification:

502 60, 502 67, 423702, 423706, 423709, 423711, 423718, 208 46, 20811101, 208135

Abstract:

A method of preparing a crystalline molecular sieve is provided, which method comprises.

US Patent:

8021643, Sep 20, 2011

Filed:

Oct 26, 2010

Appl. No.:

12/912523

Inventors:

Wenyih Frank Lai - Bridgewater NJ, US
Robert Ellis Kay - Easton PA, US

Assignee:

ExxonMobil Chemical Patents Inc. - Houston TX

International Classification:

C01B 39/46

US Classification:

423718, 423702, 423706

Abstract:

An MCM-22 family molecular sieve having an X-ray diffraction pattern of the as-synthesized MCM-22 family molecular sieve including d-spacing maxima at 12. 40. 25, 3. 570. 07 and 3. 420. 07 Angstroms and at least one peak between 26. 6 and 29 (2θ). The peak between 26. 6 to 29 (2θ) has a two theta (2θ) of about 26. 9. A method of manufacturing an MCM-22 family molecular sieve, said method comprising the steps of (a) combining at least one silicon source, at least one source of alkali metal hydroxide, at least one directing-agent (R), water, and optionally one aluminum source, to form a mixture having the following mole composition:.