J&J Chemical Consulting since Sep 1998
Principal
Adhera Technologies Jun 2004 - Mar 2009
Founder and Vice President
Shipley Company/Rohm & Haas Sep 1988 - Sep 1998
Advanced Materials Manager
Timothy G. Adams - Sudbury MA Edward K. Pavelchek - Stow MA Roger F. Sinta - Woburn MA Manuel DoCanto - Stoughton MA Robert F. Blacksmith - Hubbardston MA Peter Trefonas, III - Medway MA
The invention provides new light absorbing crosslinking compositions suitable for use as an antireflective composition (ARC), particularly suitable for short wavelength imaging applications such as 193 nm. The ARCs of the invention are preferably used with an overcoated resist layer (i. e. bottom layer ARCs) and in general comprise novel ARC resin binders that can effectively absorb reflected sub-200 nm exposure radiation.
Antireflective Coating Compositions And Exposure Methods Under 200 Nm
Timothy G. Adams - Sudbury MA Edward K. Pavelchek - Stow MA Roger F. Sinta - Woburn MA Manuel DoCanto - Stoughton MA Robert F. Blacksmith - Hubbardston MA Peter Trefonas, III - Medway MA
The invention provides new light absorbing crosslinking compositions suitable for use as an antireflective composition (ARC), particularly suitable for short wavelength imaging applications such as 193 nm. The ARCs of the invention are preferably used with an overcoated resist layer (i. e. bottom layer ARCs) and in general comprise novel ARC resin binders that can effectively absorb reflected sub-200 nm exposure radiation.
James W. Thackeray - Braintree MA James F. Cameron - Boston MA Roger F. Sinta - Woburn MA
Assignee:
Shipley Company, L.L.C. - Marlborough MA
International Classification:
G03F 7039
US Classification:
4302851, 4302701, 430170, 522 59
Abstract:
The invention provides photoresist compositions comprising a resin binder having acid labile blocking groups requiring an activation energy in excess of 20 Kcal/mol. for deblocking, a photoacid generator capable of generating a halogenated sulfonic acid upon photolysis and optionally, a base additive. It has found that linewidth variation is substantially reduced when using the halogenated sulfonic aced generator in a process involving a high temperature post exposure bake.
Dyed Photoresists And Methods And Articles Of Manufacture Comprising Same
Roger F. Sinta - Woburn MA Thomas M. Zydowsky - Cambridge MA
Assignee:
Shipley Company, L.L.C. - Marlborough MA
International Classification:
G03F 7004
US Classification:
4302701, 430326, 430926
Abstract:
The present invention provides new photoresist compositions that comprise a resin binder, a photoactive component, particularly an acid generator, and a low molecular weight anthracene dye compounds. It has been found that these dye compounds can significantly reduce or even eliminate undesired reflections of exposure radiation, particularly deep U. V. exposure radiation such as 248 nm, as well as function as effective sensitizer compounds, enabling effective imaging at higher wavelengths, particularly I-line exposures.
Hydroxyphenyl Copolymers And Photoresists Comprising Same
Hiroshi Ito - San Jose CA Ashish Pandya - Natick MA Roger F. Sinta - Woburn MA
Assignee:
Shipley Company, L.L.C. - Marlborough MA
International Classification:
G03C 173
US Classification:
4302701, 430910, 430914, 430326, 5263292
Abstract:
The present invention relates to new copolymers and use of such copolymer as a resin binder component for photoresist compositions, particularly chemically-amplified positive-acting resists. Polymers of the invention include repeat units of 1) meta-hydroxystyrene groups, 2) para-hydroxystyrene groups, and 3) photoacid-labile groups.
Theodore H. Fedynyshyn - Sudbury MA Roderick R. Kunz - Acton MA Michael Sworin - Tyngsboro MA Roger Sinta - Woburn MA
Assignee:
Massachusetts Institute of Technology - Cambridge MA
International Classification:
G03F 7004
US Classification:
4302701, 430907, 430914
Abstract:
The present invention provides photoresist materials for use in photolithography at wavelengths less than about 248 nm. More particularly, the photoresists of the invention are particularly suited for use in 157 nm lithography. A photoresist composition of the invention includes a polymer having at least one monomeric unit having an aromatic moiety. The monomeric unit further includes at least a group, such as an electron withdrawing group, attached to the aromatic moiety. The attached group includes at least one CF bond. The polymer further includes an acidic hydroxyl group. A photoresist composition of the invention can have an absorbance in a range of 1-5 m at 157 nm, rendering it particularly suitable for use as a single layer resist in 157 nm lithography.
James W. Thackeray - Braintree MA, US James F. Cameron - Cambridge MA, US Roger F. Sinta - Woburn MA, US
Assignee:
Shipley Company, L.L.C. - Marlborough MA
International Classification:
G03F 7/00
US Classification:
430326
Abstract:
The invention provides photoresist compositions comprising a resin binder having acid labile blocking groups requiring an activation energy in excess of 20 Kcal/mol. for deblocking, a photoacid generator capable of generating a halogenated sulfonic acid upon photolysis and optionally, a base additive. It has been found that linewidth variation is substantially reduced when using the halogenated sulfonic acid generator in a process involving a high temperature post exposure bake.
James W. Thackeray - Braintree MA, US James F. Cameron - Cambridge MA, US Roger F. Sinta - Woburn MA, US
Assignee:
Shipley Company, L.L.C. - Marlborough MA
International Classification:
G03F 7/039
US Classification:
4302701, 430921
Abstract:
Photoresist compositions having a resin binder with an acid labile blocking group with an activation energy in excess of 20 Kcal/mol. for deblocking, a photoacid generator capable of generating a halogenated sulfonic acid upon photolysis and optionally, a base.
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