Lawrence L. Murrell - South Plainfield NJ Rudolf A. Overbeek - Chatham Township NJ Yun-feng Chang - Chatham NJ Nelleke Van Der Puil - Hoboken NJ Chuen Y. Yeh - Edison NJ
This invention relates to the synthesis of large pore composite molecular sieves and to the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted. For example, the invention contemplates retention of the particle size in a final molecular sieve-containing product that corresponds with that of an amorphous cation oxide-framework nutrient used in its manufacture. This invention drives the selection of process conditions to achieve one or more of macro and meso porosity (âlarge pore composite porosityâ) in the final molecular sieve product as a direct product of the hydrothermal reaction producing the molecular sieve.
Selective Hydrogenation Process And Catalyst Therefor
Rudolf A. Overbeek - Chatham Township NJ Robert E. Trubac - Ridgewood NJ Chiung Yuan Huang - Glen Ridge NJ Marino Rota - Othmarsingen, CH Nelleke van der Puil - Hoboken NJ
Assignee:
ABB Lummus Global Inc. - Bloomfield NJ
International Classification:
C07C 7163
US Classification:
585260, 585258, 585259
Abstract:
A process of selectively hydrogenating an impurity in a feed containing hydrocarbons, such as, for example, an impurity selected from the group consisting of acetylene compounds, dienes, and mixtures thereof in a feed containing at least one monoolefin and the impurity wherein the impurity is hydrogenated selectively in the presence of a selective hydrogenation catalyst supported on a particulate support. The supported catalyst is supported on a mesh-like structure.
Chuen Y. Yeh - Edison NJ Lawrence L. Murrell - South Plainfield NJ Robert E. Trubac - Ridgewood NJ Rudolf A. Overbeek - Chatham Township NJ Chiung Y. Huang - Glen Ridge NJ Cemal Ercan - Bloomfield NJ Nelleke Vander Puil - Hoboken NJ Herbert E. Barner - Kinnelon NJ
A process for selectively oxidizing an organic molecule by reacting said organic molecule and oxygen in the presence of a selective oxidation catalyst supported on a mesh-like structure.
Conversion Of Nitrogen Oxides In The Presence Of A Catalyst Supported On A Mesh-Like Structure
Joakim A. Carlborg - Växjö, SE Yun-Feng Chang - Randolph NJ Lawrence L. Murrell - South Plainfield NJ Robert E. Trubac - Ridgewood NJ Rudolf A. Overbeek - Chatham Township NJ Verena R. Schmidt - Zurich, CH Chuen Y. Yeh - Edison NJ Lothar Schuh - Plankstadt, DE
Assignee:
ABB Lummus Global, Inc. - Bloomfield NJ
International Classification:
B01D 5356
US Classification:
422180, 422171, 422177, 422222
Abstract:
An apparatus for converting at least one nitrogen oxide, such as NO, NO , or N O converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide. In one embodiment, corrugated mesh-like sheets are arranged in series with a ceramic solid monolith structure with the corrugated sheets initially receiving the fluid with the at least one nitrogen oxide to be converted and which fluid then flows into the monolith structure to complete the conversion. In other embodiments, the mesh-like structure may have different configurations including a honeycomb arrangement and may include metal, metal and ceramic or ceramic and may be fibrous.
Conversion Of Nitrogen Oxides In The Presence Of A Catalyst Supported On A Mesh-Like Structure
Joakim A. Carlborg - Växjö, SE Yun-Feng Chang - Randolph NJ, US Lawrence L. Murrell - South Plainfield NJ, US Robert E. Trubac - Ridgewood NJ, US Rudolf A. Overbeek - Chatham Township NJ, US Verena R. Schmidt - Zurich, CH Chuen Y. Yeh - Edison NJ, US Lothar Schuh - Plankstadt, DE
Assignee:
ABB Lummus Global, Inc. - Bloomfield NJ
International Classification:
B01J008/00 C01B021/00
US Classification:
4232391, 4232132
Abstract:
An apparatus for converting at least one nitrogen oxide, such as NO, O, or NO converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide. In one embodiment, corrugated mesh-like sheets are arranged in series with a ceramic solid monolith structure with the corrugated sheets initially receiving the fluid with the at least one nitrogen oxide to be converted and which fluid then flows into the monolith structure to complete the conversion. In other embodiments, the mesh-like structure may have different configurations including a honeycomb arrangement and may include metal, metal and ceramic or ceramic and may be fibrous.
Rudolf Overbeek - The Woodlands TX, US Nelleke van der Puil - Amsterdam, NL Chuen Y. Yeh - Edison NJ, US Lawrence L. Murrell - Plainfield NJ, US Yun-Feng Chang - Kemah TX, US Philip Jay Angevine - Woodbury NJ, US Johannes Hendrik Koegler - Heidelberg, DE
A method for making a zeolite includes providing a reaction mixture containing mixed inorganic oxides and an organic templating agent, heating the reaction mixture, removing the templating agent at a temperature of no greater than 550 C. and under conditions such that the resulting zeolite is has an AAI of at least 1. 2. The zeolite is preferably zeolite beta, TEA-mordenite or TEA-ZSM-12.
RUDOLF A. OVERBEEK - CHATHAM TOWNSHIP NJ, US ROBERT TRUBAC - RIDGEWOOD NJ, US VINCENT A. STRANGIO - WEST ORANGE NJ, US BETTINA PAIKERT - OBERROHRDORF, CH JONATHAN LLOYD - BADEN, CH TIMOTHY ALBERT GRIFFIN - ENNETBADEN, CH REBEI BEL FDHILA - VAESTERAAS, SE
International Classification:
B01D053/18 B01D047/00
US Classification:
422/211000, 422/190000, 261/112200, 422/113000
Abstract:
A structured packing (which may or may not include a catalyst) formed from a mesh material having pore openings of less than 50 microns wherein the packing is provided with turbulence generators to promote flow of fluid through the pore openings and may be further provided with additional openings larger than the pores to improve bulk mixing.
LAWRENCE L. MURRELL - SOUTH PLAINFIELD NJ, US FRITS M. DAUTZENBERG - MAHWAH NJ, US RUDOLF A. OVERBEEK - CHATHAM TOWNSHIP NJ, US BRUCE J. TATARCHUK - AUBURN AL, US
A catalytic reactor and process wherein the reactor contains a fixed catalyst bed comprised of at least one layer of a mesh having catalyst particles and/or catalyst fibers retained in the interstices of the mesh, wherein the catalyst particles have an average particle size of no greater than 200 microns and the fibers have a diameter of no greater than 500 microns and wherein the wire mesh layer has a void volume of at least 45%.