Kameswara R. Vyakaranam - Pearland TX, US Ling Zhang - Missouri City TX, US William A. Koonce - Pearland TX, US Sara Arshad - West Springfield MA, US Venkat S. Minnikanti - Pearland TX, US Dwight D. Latham - Clute TX, US Phillip S. Athey - Lake Jackson TX, US
Assignee:
DOW GLOBAL TECHNOLOGIES LLC - Midland MI
International Classification:
C08G 18/70
US Classification:
528 29
Abstract:
Embodiments of the invention provide for compositions including a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer comprises a reaction product of at least a isocyanate capped hydrosilylated polymer and a polyol having a nominal functionality of at least 2 which is at least one of a polycarbonate polyol, a natural oil based polyol, a polyoxyalkyleneamine, a difunctional aromatic amine, a polybutyloxide polyether polyol, and a polytetramethylene glycol.
Ling Zhang - Missouri City TX, US Kamesh R. Vyakaranam - Pearland TX, US Sara Arshad - West Springfield MA, US William A. Koonce - Pearland TX, US
Assignee:
DOW GLOBAL TECHNOLOGIES LLC - Midland MI
International Classification:
C08G 18/38
US Classification:
524590, 525460
Abstract:
Embodiment of the invention provide for compositions having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer may include a reaction product of at least a polyol having a nominal functionality of at least 2 and a isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer may include a reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer may include a reaction product of a the reaction of at least a) a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 5000 and b) a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule.
Kamesh R. Vyakaranam - Pearland TX, US Ling Zhang - Missouri City TX, US Venkat S. Minnikanti - Pearland TX, US Dwight Latham - Clute TX, US Sara Arshad - West Springfield MA, US Rajat Duggal - Pearland TX, US William A. Koonce - Pearland TX, US
Assignee:
DOW GLOBAL TECHNOLOGIES LLC - Midland MI
International Classification:
C08L 71/00
US Classification:
524838
Abstract:
Moisture curable compositions including silylated polymers and methods for producing the same are provided. A two component moisture curable system for producing a cured or cross-linked silylated polymer having improved compression set properties is provided. The two component system comprises a first formulation and a second formulation. The first formulation comprises a silylated polymer, water, and filler and the second formulation comprises the silylated polymer, a curing catalyst comprising at least one Brønsted acid, and a moisture scavenger. The final cured formulation may have a compression set, determined by ASTM D395 or ISO 815-1, of less than 100%, and in some examples less than 50% and in some examples less than 15%. This demonstrated improvement in compression set not only allows the silylated polymers to be used in applications where cyclic loads are applied but also enhances product durability.
Name / Title
Company / Classification
Phones & Addresses
Sara Arshad Director
NEW ERA INC
39 Rochelle St, West Springfield, MA 01089 West Springfield, MA 01089
Wis International
Auditor
The Dow Chemical Company Jul 2008 - Mar 2011
Engineer
Henkel Loctite Corporation May 2007 - Aug 2007
Lab Technician In One-Part Silicone Technology
Education:
University of Massachusetts Amherst 2006 - 2008
Bachelors, Bachelor of Science, Chemical Engineering, Engineering
University of Massachusetts
Skills:
Adhesives Chemical Engineering Process Engineering R&D Manufacturing Six Sigma Polymers Process Simulation Chemistry Design of Experiments
The Dow Chemical Company Freeport, TX Jul 2008 to Mar 2011 Research Engineer in Polyurethanes TS&DHenkel Loctite Corporation Rocky Hill, CT May 2007 to Aug 2007 Lab Technician in one-part silicone technology
Education:
University of Massachusetts Amherst, College of Engineering Amherst, MA May 2008 Bachelors of Science in Chemical Engineering
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