Abstract:
Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A)(Si,A)(O,A):Eu, where Ais at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; Ais a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; Ais a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1. 5 and 2. 5, both inclusive. The formula is written to indicate that the Acation replaces Sr; the Acation replaces Si, and the Aanion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).