William J. Begley - Webster NY Drake M. Michno - Webster NY Hans G. Ling - Rochester NY Teh H. Chen - Fairport NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 732 G03C 734
US Classification:
430382
Abstract:
A photographic element comprises a support bearing at least one photographic silver halide emulsion layer and at least one coupler (A) having a water solubilizing group wherein coupler (A) forms a compound that is washed out of the photographic element during photographic processing and forms a coupling-off group represented by the formula: --X--Rel. sup. 2 --T. sup. 2 --INH wherein; X is selected from oxygen, nitrogen or sulfur; X--Rel. sup. 2 contains a photographic ballast and is a releasing group for releasing T. sup. 2 --INH from X--Rel. sup. 2 by elimination electron transfer reaction during photographic processing without substantial delay of releasing; T. sup. 2 is a timing group that releases INH by elimination electron transfer reaction with timing delay during photographic processing; INH is a development inhibitor group. The photographic coupler (A) enables formation of easily removable dyes in photographic elements and processes that provide images having improved acutance, stability and interimage effects.
Photographic Element Containing A Coupler Capable Of Releasing A Photographically Useful Group
William James Begley - Webster NY Teh Hsuan Chen - Fairport NY Frank Dino Coms - Fairport NY Donald Singleton - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 7305
US Classification:
430382
Abstract:
A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula ##STR1## wherein COUP is a coupler moiety having a coupling site to which T. sup. 1 is attached; T. sup. 1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated chain, or by nucleophilic displacement reaction, to release from HETERO; HETERO is a heterocyclic group containing at least two heteroatoms independently selected from oxygen, nitrogen, or sulfur, wherein one of the heteroatoms is directly attached to T. sup. 1 ; R. sup. 1 and R. sup. 2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; and PUG is a photographically useful group.
Photographic Coupler Capable Of Releasing A Photographically Useful Group
William James Begley - Webster NY Teh Hsuan Chen - Fairport NY Frank Dino Coms - Fairport NY Donald Singleton - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 108 G03C 726 G03C 732
US Classification:
430544
Abstract:
A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula ##STR1## wherein COUP is a coupler moiety having a coupling site to which T. sup. 1 is attached; T. sup. 1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated chain, or by nucleophilic displacement reaction, to release from HETERO; HETERO is a heterocyclic group containing at least two heteroatoms independently selected from oxygen, nitrogen, or sulfur, wherein one of the heteroatoms is directly attached to T. sup. 1 ; R. sup. 1 and R. sup. 2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; and PUG is a photographically useful group.
Photographic Material And Process Comprising A Coupler Capable Of Forming A Wash-Out Dye (C/C)
William J. Begley - Webster NY Drake M. Michno - Webster NY Hans G. Ling - Rochester NY Teh H. Chen - Fairport NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 732 G03C 734
US Classification:
430382
Abstract:
A photographic element comprises a support bearing at least one photographic silver halide emulsion layer and at least one coupler (A) having a water solubilizing group wherein coupler (A) forms a compound that is washed out of the photographic element during photographic processing and forms a coupling-off group represented by the formula: --X--Rel. sup. 3 --T. sup. 3 --INH wherein; X is selected from oxygen, nitrogen or sulfur X--Rel. sup. 3 contains a photographic ballast and is a releasing group for releasing T. sup. 3 --INH from X--Rel. sup. 3 by intramolecular displacement reaction during photographic processing without substantial delay of releasing; T. sup. 3 is a timing group that releases INH by intramolecular displacement reaction with timing delay during photographic processing; INH is a development inhibitor group; The photographic coupler (A) enables formation of easily removable dyes in photographic elements and processes that provide images having improved acutance, stability and interimage effects.
Photographic Element Containing A Coupler Capable Of Releasing A Photographically Useful Group
William James Begley - Webster NY Teh Hsuan Chen - Fairport NY Donald Singleton - Rochester NY Frank Dino Coms - Fairport NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 7305 G03C 740
US Classification:
430544
Abstract:
A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula COUP--T. sup. 1 --T. sup. 2 --(T. sup. 3). sub. b --PUG wherein COUP is a coupler moiety having a coupling site to which T. sup. 1 is attached; T. sup. 1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated or unconjugated chain, or by nucleophilic displacement reaction, to release T. sup. 2, T. sup. 2 being an indazole timing or linking group which, after release from T. sup. 1, functions by electron transfer down a conjugated chain to release T. sup. 3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T. sup. 1 and *** denotes the point of attachment to T. sup.
William James Begley - Webster NY Teh Hsuan Chen - Fairport NY Donald Singleton - Rochester NY Frank Dino Coms - Fairport NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
C07D40312 C07D40314 C07D23156
US Classification:
534651
Abstract:
A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula COUP--T. sup. 1 --T. sup. 2 --(T. sup. 3). sub. b --PUG wherein COUP is a coupler moiety having a coupling site to which T. sup. 1 is attached; T. sup. 1 and T3 are timing or linking groups; T. sup. 2 is an indazole timing or linking group which, after release from T. sup. 1, functions by electron transfer down a conjugated chain to release T. sup. 3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T. sup. 1 and *** denotes the point of attachment to T. sup. 3 or PUG; R. sup. 1 and R. sup. 2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; V is independently a substituent group as further defined; q is 0, 1, 2, 3 or 4; b is 0 or 1; and PUG is a photographically useful group.
William J. Begley - Webster NY Teh H. Chen - Fairport NY David S. Bailey - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 738 G03C 732
US Classification:
430382
Abstract:
Photographic compound (A) capable, upon oxidative coupling, of forming a dye, comprises in the coupling position, a coupling-off group that comprises in sequence, a releasable benzotriazole group attached to a triazole, tetrazole, oxadiazole, thiaoxadiazole, or thiadiazole inhibitor group represented by the formula: ##STR1## wherein R. sub. a, R. sub. b, R. sub. c R. sub. 1, R. sub. 2 and Q are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process to provide improved images.