The present invention relates to an apparatus and a process for the high-throughput, quick screening, optimization, regeneration, reduction and activation of catalysts. More specifically, the present invention is a method and apparatus to quickly screen, optimize and regenerate multiple fast deactivating catalysts while maintaining a predefined range of time-on-stream.
Deep Hydrodesulfurization Of Hydrocarbon Feedstreams
Teh C. Ho - Bridgewater NJ, US Garland B. Brignac - Clinton LA, US Zhiguo Hou - Nazareth PA, US Michael C. Kerby - Center Valley PA, US Tahmid I. Mizan - Bridgewater NJ, US William E. Lewis - Baton Rouge LA, US
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
The distillate catalytic hydrodesulfurization of hydrocarbon fuels wherein the optimum hydrogen treat gas rate to maximize desulfurization is determined and introduced into the reaction zone to maintain a controlled amount of hydrogen at the surface of the catalyst during hydrodesulfurization.
Teh C. Ho - Bridgewater NJ, US Stuart L. Soled - Pittstown NJ, US Kuangnan Qian - Belle Mead NJ, US Stephen J. McCarthy - Center Valley PA, US Andrew C. Moreland - Boerne TX, US
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
The present invention relates to a catalytic process for removing organonitrogen species from hydrocarbon mixtures such as refinery process feedstreams. More particularly, this invention relates to a new operating and catalyst loading strategies based on organonitrogen concentration, composition, and structure.
Methods For Identifying High Fouling Hydrocarbon And For Mitigating Fouling Of Process Equipment
Teh C. Ho - Bridgewater NJ, US Glen B. Brons - Phillipsburg NJ, US Limin Song - West Windsor NJ, US Tahmid I. Mizan - Coppell TX, US
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
International Classification:
G01N 25/20
US Classification:
436147, 208 18, 208 19, 208 48 R
Abstract:
Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.
Methods For Mitigating Fouling Of Process Equipment
Teh C. HO - Bridgewater NJ, US Glen B. BRONS - Phillipsburg NJ, US
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
International Classification:
C10G 9/16 G01N 31/00
US Classification:
208 48AA, 436 2
Abstract:
Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter indicative of the fouling propensity by a regression of a series of temperature measurements data for the hydrocarbon stream exiting a test unit. In another method, an effective minimal amount of an antifoulant is added to a hydrocarbon stream to reduce fouling, where the amount of the antifoulant is determined based on the fouling propensity of the hydrocarbon stream.
Use Of Low Boiling Point Aromatic Solvent In Hydroprocessing Heavy Hydrocarbons
This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially less hydrogen is absorbed during the process relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component contains at least one single ring aromatic compound and has a relatively low boiling point range compared to the heavy hydrocarbon oil component used as another co-feed component.
Use Of Supercritical Fluid In Hydroprocessing Heavy Hydrocarbons
This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially longer run length can be attained relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component is comprised of at least one or more supercritical solvent compounds.
Dispersed Metal Sulfide Catalysts For Hydroprocessing (Law105)
Teh Chung Ho - Bridgewater NJ Stuart Leon Soled - Pittstown NJ Sabato Miseo - Pittstown NJ Gary Brice McVicker - Califon NJ Michel Daage - Baton Rouge LA Viktor Buchholz - Branchburg NJ
Assignee:
Exxon Research and Engineering Company - Florham Park NJ
International Classification:
C07C 510
US Classification:
585266
Abstract:
The present invention is directed toward a catalyst composition prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100. degree. to about 120. degree. C. followed by calcining said support at a temperature of about 400. degree. to about 600. degree. C. ; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo. sub. y W. sub. 1-y O. sub. 4). sub. a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0. 5. ltoreq. a. ltoreq. 3 when Cr is one of the promoter metals. (d) sulfiding said deposited or composited support of step (c) with an excess amount of sulfur in the form of one or more sulfur bearing compounds and at a temperature of at least about 250. degree. C.
License Records
Teh I Ho
License #:
MT013773T - Expired
Category:
Medicine
Type:
Graduate Medical Trainee
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