Kenneth W. Skaggs - Lake Jackson TX Robert B. Turner - Lake Jackson TX Terry L. Lamb - Ringgold GA
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B32B 326 B05D 500
US Classification:
4283186
Abstract:
Substrates having successive layers of a cellular polyurethane and a noncellular polyurethane are prepared using certain siloxane-polyether block copolymers in the noncellular polyurethane formulation. The use of the block copolymer reduces or eliminates the formation of a bubble line at the interface of the polyurethane layers, thereby improving physical and cosmetic properties of the carpet.
Phillip L. Wing - Cohutta GA James K. Jennings - Rocky Face GA Terry L. Lamb - Ringgold GA
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B05D 302
US Classification:
4273741
Abstract:
A process for preparing a substrate backed with a polymer derived from an organic polyisocyanate, said process comprising the steps of (a) forming a precoat layer of a precoat reaction mixture comprising a substantially difunctional polyahl and a substantially difunctional organic polyisocyanate, (b) separately forming a capcoat layer of a capcoat reaction mixture comprising a polyahl and a polyisocyanate, (c) contacting said precoat layer with one surface of said substrate before said precoat layer is cured to a tack-free state, (d) contacting said capcoat layer with one surface of said precoat layer before at least one of said precoat layer and capcoat layer is cured to a tack-free state, (e) completing curing said capcoat and precoat layer, and (f) cooling the resulting polymer-backed substrate to a temperature less than about 35. degree. C. before any mechanical distortion thereof, wherein steps (a)-(f) are carried out under conditions such that mechanically induced stress in the substrate, precoat layer and capcoat layer is minimized. Another aspect of this invention is a polymer backed-substrate comprising (a) a substrate (b) attached to a surface of said substrate a precoat layer of a polymer formed by the reaction of a substantially difunctional polyahl and a substantially difunctional organic polyisocyanate, which precoat layer is overcoated with (c) a capcoat layer comprising a polymer formed by the reaction of a polyahl and an organic polyisocyanate.
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