Thomas Kent Day

US Patent:

57169039, Feb 10, 1998

Filed:

Jan 3, 1997

Appl. No.:

8/778890

Inventors:

Richard M. Kramer - Chesterfield MO
Thomas M. Day - Creve Coeur MO
Ralph E. Lindemann - St. Louis MO
Jane L. Gillespie - University City MO

Assignee:

Monsanto Company - St. Louis MO

International Classification:

A01N 5702

US Classification:

504206

Abstract:

Solid N-phosphonomethylglycine or glyphosate acid is charged to a substantially closed system and then partially pre-dried as by continuously recirculating it through a hot air grinding/drying system. A cooled solution of ammonium hydroxide is then metered into and reacted with the partially dried glyphosate acid as it is being recirculated in a manner such that the moisture content of the reaction mass so formed is continuously decreased throughout the reaction. Following completion of the ammonium hydroxide addition, a powdered reaction mass/product having a moisture content of about 2 wt. % is formed. Significantly, at this stage, the ammonium glyphosate product is suitable for end use and it can be readily dissolved in water and immediately used as a herbicide or plant growth regulator. More importantly, however, this product is capable due to its highly sorptive character to be further formulated into a product exceptionally highly loaded with adjuvants and particularly surfactants.

US Patent:

56333978, May 27, 1997

Filed:

Jun 7, 1995

Appl. No.:

8/485316

Inventors:

Jane L. Gillespie - University City MO
Thomas M. Day - Creve Coeur MO
Richard M. Kramer - Chesterfield MO

Assignee:

Monsanto Company - St. Louis MO

International Classification:

C07F 938

US Classification:

562 17

Abstract:

Solid N-phosphonomethylglycine or glyphosate acid in "wet cake" form is charged to a suitable mixer/reactor. A stoichiometric equivalent of anhydrous ammonia gas is fed to the mixer for direct reaction with the glyphosate acid as it is agitated within the mixer. A water Jacket containing circulating water or other suitable heat transfer facilitating means readily known to those in the art is adapted to the mixer and used to remove heat from the reactor produced by the exothermic reaction. The moisture content of the glyphosate wet cake, the design of the mixer including a preferred close tolerance relation between the inner walls of the reactor and its mixing impellers together with the relative location of the ammonia gas inlet in the mixer/reactor and maintenance of a reaction temperature of about 60. degree. C. or below are all important process variables. The ammonium glyphosate thereby produced is a highly sorptive, water-soluble powder suitable for end use as a plant growth regulator or as a herbicide without further processing.

US Patent:

56144687, Mar 25, 1997

Filed:

Jun 7, 1995

Appl. No.:

8/472152

Inventors:

Richard M. Kramer - Chesterfield MO
Thomas M. Day - Creve Coeur MO
Ralph E. Lindemann - St. Louis MO
Jane L. Gillespie - University City MO

Assignee:

Monsanto Company - St. Louis MO

International Classification:

A01N 5702

US Classification:

504206

Abstract:

Solid N-phosphonomethylglycine or glyphosate acid is charged to a substantially closed system and then partially pre-dried as by continuously recirculating it through a hot air grinding/drying system. A cooled solution of ammonium hydroxide is then metered into and reacted with the partially dried glyphosate acid as it is being recirculated in a manner such that the moisture content of the reaction mass so formed is continuously decreased throughout the reaction. Following completion of the ammonium hydroxide addition, a powdered reaction mass/product having a moisture content of about 2 wt. % is formed. Significantly, at this stage, the ammonium glyphosate product is suitable for end use and it can be readily dissolved in water and immediately used as a herbicide or plant growth regulator. More importantly, however, this product is capable due to its highly sorptive character to be further formulated into a product exceptionally highly loaded with adjuvants and particularly surfactants.