Abstract:
A relatively simple and energy efficient multiple stage cryogenic process for the purification of a hydrogen-rich stream by the removal of acid gases, mainly COand HS, by method of autorefrigeration and delivering or producing those acid gases, mainly CO, at pressure sufficiently high for disposal by containment, commonly known as sequestration. Autorefrigeration is comprised of (a) condensing acid gases from the syngas stream by cooling the syngas, (b) separating the liquefied acid gases from the syngas, and (c) evaporating the liquefied acid gases at a pressure lower than that of the syngas to provide cooling. The process is composed of multiple autorefrigeration stages to generate multiple acid gas product streams with a pressure as high as practical in each stream so as to lessen the power needed to pressurize the acid gas streams for sequestration. The final autorefrigeration stage utilizes an antifreeze liquid that allows the final stage to operate below the freezing point of CO; thus allowing more acid gas removal. The antifreeze liquid is an alcohol or a mixture of alcohols with a freezing point lower than about minus 110 degrees F.