The conversion of long-chain alpha-olefins to methyl ketones can be efficiently carried out using reaction systems containing palladium, a co-catalyst, and an aqueous solvent system.
The production of cyclic amines by the amination of cyclic alcohols is made more efficient by carrying out the reaction in the presence of certain amine solvents.
Oxa-Organic Sulfur Compounds, Their Preparation And Use
John S. Roberts - Bartlesville OK Tod K. Shioyama - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C08F 200 C08F 238
US Classification:
526209
Abstract:
Oxa-organic sulfur compounds, methods of preparing such compounds and methods of using the compounds as polymer chain length terminating agents are provided. The compounds are prepared by reacting allyl alcohol in the presence of a basic catalyst with a compound having the formula ##STR1## to form an intermediate. The intermediate is then reacted with hydrogen sulfide in the presence of ultraviolet radiation and a trialkyl phosphite to form the oxa-organic sulfur compound having the formula ##STR2##.
Tod K. Shioyama - Bartlesville OK Jim J. Straw - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C07C 4527 C07C 4534 B01J 3140 B01J 2396
US Classification:
568401
Abstract:
Wacker-type oxidation catalysts can be recovered and rejuvenated for further use by separating catalyst solids from the reaction mixture and, optionally, adjusting pH.
Oxa-Organic Sulfur Compounds, Their Preparation And Use
John S. Roberts - Bartlesville OK Tod K. Shioyama - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C07C14800 C07C14914
US Classification:
568 44
Abstract:
Oxa-organic sulfur compounds, methods of preparing such compounds and methods of using the compounds as polymer chain length terminating agents are provided. The compounds are preparated by reacting allyl alcohol in the presence of a basic catalyst with a compound having the formula ##STR1## to form an intermediate. The intermediate is then reacted with hydrogen sulfide in the presence of ultraviolet radiation and a trialkyl phosphite to form the oxa-organic sulfur compound having the formula ##STR2##.
Oxa-Organic Sulfur Compounds, Their Preparation And Use
John S. Roberts - Bartlesville OK Tod K. Shioyama - Bartlesville OK
Assignee:
Phillips Petroleum Company - Bartlesville OK
International Classification:
C07C31904 C07C32100 C07C32300
US Classification:
568 50
Abstract:
Oxa-organic sulfur compounds, methods of preparing such compounds and methods of using the compounds as polymer chain length terminating agents are provided. The compounds are prepared by reacting allyl alcohol in the presence of a basic catalyst with a compound having the formula ##STR1## to form an intermediate. The intermediate is then reacted with hydrogen sulfide in the presence of ultraviolet radiation and a trialkyl phosphite to form the oxa-organic sulfur compound having the formula ##STR2##.
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