Articles are formed from a thermosetting composition based on polybutadiene or polyisoprene resins which are subjected to a high temperature cure step of greater than 250Â C. The thermosetting compositions may include fillers such as particulate ceramic fillers and may also include woven webs for improved dimensional stability and decreased brittleness. The formation process of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated on one or both opposed surfaces to metal conductive foil (e. g. , copper).
Process For Forming Hard Shaped Molded Article Of A Cross-Linked Liquid Polybutadiene Or Polyisoprene Resin And A Butadiene Or Isoprene Containing Solid Polymer And Resulting Articles
Vincent R. Landi - Danielson CT J. Mark Mersereau - Brooklyn CT Walter A. Robbins - Dayville CT
Assignee:
Rogers Corporation - Rogers CT
International Classification:
C08C 1100 C08D 902
US Classification:
524571
Abstract:
A forming process for producing a hard shaped molded article that includes subjecting a moldable thermosetting composition to a high temperature cure condition at a temperature greater than about 250. degree. C. and less than the decomposition temperature of the composition to form a crosslinked polymeric network. In particular, the invention features a forming process for producing a hard shaped molded article that includes the steps of (a) providing a moldable thermosetting composition that includes 1) a polybutadiene or polyisoprene resin which is a liquid at room temperature and which has a molecular weight less than 5,000 and a large number of pendent vinyl groups and 2) a solid butadiene- or isoprene-containing polymer (e. g, a thermoplastic elastomer); (b) forming the composition into a shape; and (c) curing the composition to produce the article including subjecting the composition to a high temperature cure condition at a temperature greater than about 250. degree. C. and less than the decomposition temperature of the composition.
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