Diankui Fu - Missouri City TX, US Yiyan Chen - Richmond TX, US Zhijun Xiao - Kuala Lumpur, MY Mathew Samuel - Al-Khobar, SA Sylvie Daniel - Jouy en Josas, FR
Assignee:
Schlumberger Technology Corporation - Sugar Land TX
International Classification:
C09K 8/52 C09K 5/58 C09K 8/60
US Classification:
507244, 507240, 507272, 507277
Abstract:
A viscous aqueous high density well treatment fluid composition stable at high temperature containing a surfactant and inorganic salts is described. Methods of preparing the fluid and increasing the stability and viscosity of the fluid are given. The fluid is useful for wellbore cleanout, hydraulic fracturing, gravel packing, completion, acid diversion, lost circulation reduction, well killing, cementing, selective water shutoff, and fracture fluid diversion.
Philip F. Sullivan - Bellaire TX, US Belgin Baser - Houston TX, US Carlos Abad - Richmond TX, US Yiyan Chen - Richmond TX, US Mehmet Parlar - Sugar Land TX, US Gregory Kubala - Houston TX, US
Assignee:
Schlumberger Technology Corporation - Sugar Land TX
Delayed breakers are given that break viscoelastic surfactant fluids inside the pores of formations into which the fluids have been injected. The breakers comprise proteins, proteins that contain breakers, or cells that contain breakers. Proteins become breakers, and proteins and cells release breakers, due to a triggering mechanism that may be, for example, a change in temperature, pH, or salinity.
An aqueous viscoelastic surfactant (VES) fluid foamed or energized with carbon dioxide, in which the VES is more compatible with the carbon dioxide, is made by the addition of one or more than one synergistic co-surfactant. The synergist co-surfactant includes quaternary amines and ethoxylated carboxylates having a hydrophobic chain shorter than the hydrophobic chain of the VES. Improved compatibility is evidenced for a given surfactant concentration either by formation and maintenance of a foam under conditions at which the foam could not otherwise have been formed or maintained, or by either higher viscosity of the foamed fluid at a given temperature or longer foam life at a given temperature or a higher temperature at which useful fluid viscosity can be generated or maintained for a useful time. The aqueous carbon dioxide foamed fluids may be used in acidizing, acid fracturing, gravel packing, diversion, and well cleanout.
Composition and method for shortening the shear recovery time of cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a co-gelling agent selected from triblock oligomeric compounds having hydrophilic (for example polyether) and hydrophobic (for example alkyl) portions. The co-gelling agent also increases fluid viscosity and very low co-gelling agent concentration is needed. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.
Jesse Lee - Sugar Land TX, US Yiyan Chen - Richmond TX, US Timothy Pope - Sugar Land TX, US Eric Hanson - San Diego CA, US Samuel Cozzens - Rock Springs WY, US Taner Batmaz - Rock Springs WY, US
Assignee:
Schlumberger Technology Corporation - Sugar Land TX
International Classification:
C09K 8/584 C09K 8/588 E21B 21/00
US Classification:
507261, 507260, 507266, 507267, 1663082
Abstract:
A method for shortening the shear recovery time of zwitterionic viscoelastic surfactant fluids by adding a rheology enhancer having the structure:R-(EO)(PO)—R′—OHin which R is an alkyl group that is straight chained or branched, saturated or unsaturated, and contains from 3 to about 18 carbon atoms, x is from 0 to about 14, y is from 0 to about 7, R′ is an alkyl group that contains from 0 to about 14 carbon atoms and is straight chained, branched if having more than 3 carbon atoms, saturated, unsaturated if having more than one carbon atom, the total number of carbon atoms in R plus R′ is from 3 to about 21, and the EO and PO groups, if present, may be in any order. The rheology enhancer also increases fluid viscosity and thermal stability. Preferred surfactants are betaines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.
A method for increasing the foam stability of foams made with cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of an amphiphilic polymeric foam stabilizer containing at least one portion that is a partially hydrolyzed polyvinyl ester or partially hydrolyzed polyacrylate. The foam stabilizer allows foams to be used at temperatures at which the unfoamed fluids would not have stable viscosity, and allows use of lower viscoelastic surfactant concentrations in the liquid phase. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.
Yiyan Chen - Richmond TX, US Jesse C. Lee - Paris, FR Fang Li - Pleasanton CA, US Manilal Dahanayake - Princeton Junction NJ, US Robert Tillotson - Toms River NJ, US Allwyn Colaco - South River NJ, US
Assignee:
Schlumberger Technology Corporation - Sugar Land TX
A method for increasing the rate of shear rehealing of fluids made with cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a rheology enhancer package containing, for example a polyethylene glycol-polypropylene glycol block copolymer and a polynaphthalene sulfonate. The rheology enhancer package allows viscoelastic surfactant fluids to be used at lower viscoelastic surfactant concentrations in certain applications, for example certain oilfield treatments, for example fracturing and gravel packing. Preferred surfactants are betaines and quaternary amines.
A method for shortening the shear recovery time of cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of an amphiphilic polymeric rheology enhancer containing at least one portion that is a partially hydrolyzed polyvinyl ester or partially hydrolyzed polyacrylate. The rheology enhancer also increases fluid viscosity and very low rheology enhancer concentration is needed. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.
Schlumberger
Principal Engineer, Production Technology
Schlumberger Mi Swaco Sep 2013 - Jun 2017
Team Leader, Product Development
Schlumberger Oct 2011 - Aug 2013
Chemistry Discipline Leader, Dasas
Schlumberger 2009 - 2011
Project Manager
Schlumberger 2009 - 2011
Principal Chemical Engineer
Education:
Michigan State University 1994 - 1999
Doctorates, Doctor of Philosophy, Chemistry
University of Science and Technology of China 1984 - 1989
Skills:
Chemistry Polymers Characterization Petroleum Oil and Gas Oilfield Petroleum Engineering Stimulation Materials Science Chemical Engineering Fluids Upstream Polymer Chemistry Project Management Organic Chemistry Field Development Reservoir Engineering Product Optimization Cement Hydraulic Fracturing Nanomaterials Design of Experiments Coatings Tga Polymer Synthesis Rheology R&D Upstream Oilfield R&D Oilfield Stimulation Fluids Sand Control Fluids Project Managements R&D Strategic Planning People and Performance Managements Oilfield Stimulation Services Chemical Product Development Uv/Vis Nanotechnology Oil/Gas Spectroscopy Nmr Molecular Structure Properties Relationship Cementing Oil Corrosion