A CMP slurry is formulated with a single component oxidizer capable of oxidizing a metal undergoing planarization and yielding a complexing agent which complexes with the oxidized metal thereby minimizing overetching. Embodiments include CMP Cu with a fixed abrasive pad or an abrasive containing slurry, employing a peroxy acid, e. g. , peroxy benzoic acid, or a polyethylene glycol peroxy acid. In another embodiment, a single component is employed which dissociates in the slurry into an oxidizer and complexing agent, such as an amine-peroxy acid, e. g. , urea peroxy acid.
A CMP slurry is formulated with an oxidizer capable of oxidizing a metal undergoing planarization and yielding a complexing agent which complexes with the oxidized metal thereby minimizing overetching. The slurry may further include abrasive particles, inhibitors, pH adjusting agents, and combinations thereof.
Method And Apparatus For Enhanced Cmp Using Metals Having Reductive Properties
Stan D. Tsai - Fremont CA Yuchun Wang - Cupertino CA Kapila Wijekoon - Santa Clara CA Rajeev Bajaj - Fremont CA Fred C. Redeker - Fremont CA
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
B24D 1100
US Classification:
451526, 451533, 451538, 451539
Abstract:
Dishing in chemical mechanical polishing (CMP) is reduced by introducing a material that balances electrochemical forces. In a first embodiment of the invention, a polishing pad having copper material in grooves on the polishing pad surface is used in the polishing process to reduce dishing. In a second embodiment of the invention, the polishing pad has perforations with copper fillings. In a third embodiment of the invention, a copper retaining ring on the polishing head introduces copper material to the CMP process to reduce dishing. In a fourth embodiment of the invention, a conditioning plate of copper is used in the polishing apparatus. In a fifth embodiment of the invention, additional copper features are placed on the substrate to be polished. The polishing of the additional features introduces copper steadily through the polishing process. In a sixth embodiment of the invention, copper compounds are added to the polish slurry.
Method And Apparatus For Enhanced Cmp Using Metals Having Reductive Properties
Stan D. Tsai - Fremont CA Yuchun Wang - Cupertino CA Kapila Wijekoon - Santa Clara CA Rajeev Bajaj - Fremont CA Fred C. Redeker - Fremont CA
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
B24B 100
US Classification:
451 36, 451 41, 451533
Abstract:
Dishing in chemical mechanical polishing (CMP) is reduced by introducing a material that balances electrochemical forces. In a first embodiment of the invention, a polishing pad having copper material in grooves on the polishing pad surface is used in the polishing process to reduce dishing. In a second embodiment of the invention, the polishing pad has perforations with copper fillings. In a third embodiment of the invention, a copper retaining ring on the polishing head introduces copper material to the CMP process to reduce dishing. In a fourth embodiment of the invention, a conditioning plate of copper is used in the polishing apparatus. In a fifth embodiment of the invention, additional copper features are placed on the substrate to be polished. The polishing of the additional features introduces copper steadily through the polishing process. In a sixth embodiment of the invention, copper compounds are added to the polish slurry.
Additives To Cmp Slurry To Polish Dielectric Films
Yuchun Wang - San Jose CA Rajeev Bajaj - Fremont CA Fred C. Redeker - Fremont CA
Assignee:
Applied Materials Inc. - Santa Clara CA
International Classification:
C09K 1300
US Classification:
252 791, 252 792, 252 794, 252 795
Abstract:
A method and composition for planarizing a substrate. The composition includes one or more chelating agents, one or more oxidizers, one or more corrosion inhibitors, a polar solvent, and deionized water. The composition may further comprise one or more surfactants, one or more agents to adjust the pH and/or abrasive particles. The method comprises planarizing a substrate using a composition including a polar solvent.
Kapila Wijekoon - Santa Clara CA Stan D. Tsai - Fremont CA Yuchun Wang - Cupertino CA Doyle E. Bennett - Santa Clara CA Fred C. Redeker - Fremont CA Madhavi Chandrachood - Sunnyvale CA Brian J. Brown - Palo Alto CA
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
B24B 100
US Classification:
451 56, 451443
Abstract:
A polishing method is provided which simultaneously supplies both a polishing fluid and a conditioning fluid to a polishing pad, while a substrate is in moving contact with the polishing pad.
Ion Exchange Materials For Chemical Mechanical Polishing
Yuchun Wang - San Jose CA Stan D. Tsai - Fremont CA Kapila Wijekoon - Palo Alto CA Rajeev Bajaj - Fremont CA Fred C. Redeker - Fremont CA
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
B24B 100
US Classification:
451 41
Abstract:
Ion exchange materials are employed in CMP methodologies to polish or thin a semiconductor substrate or a layer thereon. Embodiments include a polishing pad having an ion exchange material thereon and polishing a semiconductor substrate or a layer thereon with the polishing pad or a CMP composition including an ion exchange material therein and polishing the substrate or a layer thereon with the CMP composition or both.
Yuchun Wang - San Jose CA Boguslaw Swedek - San Jose CA
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
G01N 2159
US Classification:
356436, 356246, 356440
Abstract:
A method and apparatus for measuring a slurry distribution. A slurry solution is doped with a light absorbing dye having an absorptivity sensitive to a physical parameter such as acidity, temperature or pressure. The solution is delivered between a platen and substrate in a first physical state where it absorbs light. A laser beam is generated, transmitted through the slurry layer, reflected off of the substrate, and detected by a photodetector. The thickness of the slurry is measured from its absorptivity and the transmittance of the laser beam. A relative motion between the light source and substrate allows the slurry layer thickness to be measured as a function of distance from the center of the substrate. A final water rinse removes the slurry and brings any residual slurry to a/second physical state where it does not absorb light.