Robert C. Langley - Millington NJ Herbert Myers - South Orange NJ
Assignee:
Engelhard Corporation - Iselin NJ
International Classification:
C25B 134
US Classification:
204 98
Abstract:
Platinum and iridium in catalytic electrodes for electrochemical uses is partially replaced with lead ruthenate-tantalum oxide composite. Electrodes are fabricated by first coating a film-forming metal substrate with a platinum-iridium composite undercoat, then overcoating with a composite containing lead, ruthenium, tantalum, platinum, iridium and oxygen. The most preferred anodes have a titanium substrate initially coated with approximately at least 2 gm/m. sup. 2 of 70:30. sup. w /o Pt:Ir composite, followed by about 20 gm/m. sup. 2 of a composite having the nominal composition of 22. 2. sup. w /o Pb. sub. 2 Ru. sub. 2 O. sub. 6 ; 66. 6. sup. w /o Ta. sub. 2 O. sub. 5 ; 7. 9. sup. w /o Pt and 3. 4. sup. w /o Ir. The outer layer of the prepared anode contains from about 10 to about 16. sup.
Titanium-Lead Anode For Use In Electrolytic Processes Employing Sulfuric Acid
An anode for use in electrolytic processes with an electrolyte containing sulfuric acid. The anode comprises a valve metal substrate, a lead or lead alloy antipassivation layer in contact with the valve metal substrate, and a lead ruthenate or lead iridate catalyst in surface contact with the lead or the lead alloy. Also disclosed are methods for employing the anode in electrowinning processes as well as a process for operating an electrolytic cell.
Apparatus For The Production Of Aqueous Alkali Metal Hypochlorite
An apparatus is disclosed for the electrolytic production of a solution of an aqueous alkali metal hypochlorite solution. The apparatus is especially useful for chlorinating swimming pools. The single vessel is partitioned horizontally into an upper compartment for the brine and a lower compartment serving as the electrolytic cell and provided with a removable electrode assembly with an electrode spacing of at least 0. 5 inch. Brine feeds through and evolved gas emerges through the partition.
Electrolysis Cathodes With Ag-Ti Intermetallic Coating
A cathode for use in an electrolytic process which comprises a substrate metal with a surface coating of a silver-titanium intermetallic formed in situ on the cathode.
Monolithic honeycomb structures are made by heating to a fluid condition an admixture comprising an inorganic powder and a temporary vehicle, forcing the fluid admixture through a stencil having a plurality of masking islands thereby forming a thin lamina beneath the stencil which is cooled immediately to form an essentially solid structure. This process is repeated to form a composite of successive cohered laminae thereby forming a monolithic honeycomb structure, which is heated to remove the vehicle and subsequently sintered to form a self-supporting honeycomb structure.
Glass Frit Containing Lead Ruthenate Or Lead Iridate In Relatively Uniform Dispersion And Method To Produce Same
Thick film resistive elements are prepared from an intimate admixture comprising silica, lead oxide and ruthenium dioxide or iridium dioxide which is heated to a temperature sufficient to provide a lead-containing glass having dispersed therein lead ruthenate or lead iridate. The lead-containing glass is comminuted and a resistor paste is formed which can be subsequently coated and fired on to a desired substrate to form the thick film resistive component. The method of this invention may facilitate the production of thick film resistors exhibiting a low temperature coefficient of resistivity, relative freedom from noise and drift, and high moisture resistance.
Electrical Circuit Element Comprising Thick Film Resistor Bonded To Conductor
Thick film resistive elements are prepared from an intimate admixture comprising silica, lead oxide and ruthenium dioxide or iridium dioxide which is heated to a temperature sufficient to provide a lead-containing glass having dispersed therein lead ruthenate or lead iridate. The lead-containing glass is comminuted and a resistor paste is formed which can be subsequently coated and fired on to a desired substrate to form the thick film resistive component. The method of this invention may facilitate the production of thick film resistors exhibiting a low temperature coefficient of resistivity, relative freedom from noise and drift, and high moisture resistance.
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